Gas Permeation Behavior of Single and Mixed Gas Components Using an Asymmetric Ceramic Membrane
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33090
Gas Permeation Behavior of Single and Mixed Gas Components Using an Asymmetric Ceramic Membrane

Authors: Ngozi Nwogu, Edward Gobina

Abstract:

A dip-coating process has been used to form an asymmetric silica membrane with improved membrane performance and reproducibility. First, we deposited repeatedly silica on top of a commercial alumina membrane support to improve its structural make up. The membrane is further processed under clean room conditions to avoid dust impurity and subsequent drying in an oven for high thermal, chemical and physical stability. The resulting asymmetric membrane exhibits a gradual change in the membrane layer thickness. Compared to the support, the dual-layer process improves the gas flow rates. For the scientific applications for natural gas purification, CO2, CH4 and H2 gas flow rates were. In addition, the membrane selectively separated hydrogen.

Keywords: Gas permeation, Silica membrane, separation factor, membrane layer thickness.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1107233

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2386

References:


[1] McCool B, Hill N, DiCarlo J, DeSisto W. Synthesis and characterization of mesoporous silica membranes via dip-coating and hydrothermal deposition techniques. Journal of Membrane Science. 2003; 218(1):55- 67.
[2] Tüzün FN and Arçevik E. Pore Modification in Porous Ceramic Membranes with Sol‐Gel Process and Determination of Gas Permeability and Selectivity. Macromolecular symposia: Wiley Online Library; 2010. p. 135-142.
[3] Kluiters S. Status review on membrane systems for hydrogen separation. Energy Center of the Netherlands, Petten, The Netherlands. 2004.
[4] Collins JP, Way JD. Preparation and characterization of a composite palladium-ceramic membrane. Industrial & Engineering Chemistry Research. 1993; 32(12):3006-3013.
[5] Tsai C, Tam S, Lu Y, Brinker CJ. Dual-layer asymmetric microporous silica membranes. Journal of Membrane Science. 2000; 169(2):255-268.
[6] Chung T, Jiang LY, Li Y, Kulprathipanja S. Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation. Progress in Polymer Science. 2007; 32(4):483-507.
[7] Paul DR, Yampol'skii YP. Polymeric gas separation membranes. : CRC press; 1993.
[8] Nwogu NC, Gobina E, Kajama MN. Improved carbon dioxide capture using nanostructured ceramic membranes. Low Carbon Economy. 2013; 4(03):125.
[9] Keizer K, Uhlhorn RJ, Burggraaf TJ. Gas separation using inorganic membranes. Membrane Science and Technology. 1995; 2:553-588.
[10] Sing KS. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). Pure and applied chemistry. 1985; 57(4):603- 619.
[11] Smart S, Liu S, Serra JM, Diniz da Costa JC, Iulianelli A, Basile A. 8 - Porous ceramic membranes for membrane reactors. In: Basile A, editor. Handbook of Membrane Reactors. : Woodhead Publishing; 2013. p. 298-336.
[12] Gobina E. Apparatus and method for separating gases. 2006. U.S. Patent No. 7,048,778. Washington, DC: U.S. Patent and Trademark Office
[13] Gobina E. Apparatus and method for separating gases. 2007. U.S. Patent No. 7,297,184. Washington, DC: U.S. Patent and Trademark Office.
[14] Ohwoka A, Ogbuke I, Gobina E. Performance of pure and mixed gas transport in reconfigured hybrid inorganic membranes Pt. 1. Membrane Technology. 2012; 2012(6):7-12.