Lithium Oxide Effect on the Thermal and Physical Properties of the Ternary System Glasses (Li2O3-B2O3-Al2O3)
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33093
Lithium Oxide Effect on the Thermal and Physical Properties of the Ternary System Glasses (Li2O3-B2O3-Al2O3)

Authors: D. Aboutaleb, B. Safi

Abstract:

The borate glasses are known by their structural characterized by existence of unit’s structural composed by triangles and tetrahedrons boron in different configurations depending on the percentage of B2O3 in the glass chemical composition. In this paper, effect of lithium oxide addition on the thermal and physical properties of an alumina borate glass, was investigated. It was found that the boron abnormality has a significant effect in the change of glass properties according to the addition rate of lithium oxide.

Keywords: Borate glasses, triangles and tetrahedrons boron, Lithium oxide, Boron anomaly, thermal properties, physical properties.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1099662

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2926

References:


[1] Zarzycki, j, les verres et l’état vitreux. Masson Ed, 1980, pp. 387.
[2] H. Scholze, Glass: Nature, Structure and Properties, Springer, New York, 1991.
[3] J.E. Shelby, Introduction to Glass, Science and Technologies. Immiscibility/Phase Separation, The Royal Society of Chemistry, 1997, pp. 48-67.
[4] James Barton, Claude Guillem, Les verres : science et technologie, Chimie I matériaux, Edition Edp
[5] A. Dietzel, Glass structure and glass properties: 2.Glastech, Ber. 22 1948, pp. 81-86.
[6] D. Aboutaleb, Study of phase separation on borate and borosilicate glasses, Ph.D. Thesis, Boumerdes University, Algeria, 2010.
[7] D. Aboutaleb. J. Douglad. B. Safi. O. Jbara, A. Iratni. Phase separation and chemical durability in the SiO2-B2O3-Na2O (SBN) glass system, Asian Journal of Chemistry, 24 (2), 2012, pp. 473-480.
[8] Polyakova, I, G. Phases diagrams and properties of glasses, Phys. Chem.Glasses. Alkali borosilicate system, Oct. (41), 2000, pp.253.
[9] D. Aboutaleb, A. Iratni, B. Safi; Ostwald ripening phenomena in B2O2- PbO glass system, Asian journal of chemistry, 22(3), 2010, pp. 1275- 1282.
[10] H.A. Silim, Composition effect on some physical properties and FTIR of alumino-borate glasses containing lithium, sodium, potassium and barium oxides, Egypt. J. Solids, 29 (2), 2006, pp. 293-302.
[11] A.E. Owen, Properties of glasses in the system CaO-B2O3-Al2O3: Part 1. The DC conductivity and structure of calcium boroaluminate glasses, Phys. Chem.Glasses, 2, 1961, pp. 87-98.
[12] J.F. MacDowell, Aluminoborate glass-ceramics with low thermal expansivity, J. Am. Ceram. Soc. 73, 1990, pp. 2287-2292.