Gradations in Concentration of Heavy and Mineral Elements with Distance and Depth of Soil in the Vicinity of Auto Mechanic Workshops in Sabon Gari, Kaduna State, Nigeria
Authors: E. D. Paul, H. Otanwa, O. F. Paul, A. J. Salifu, J. E. Toryila, C. E. Gimba
Abstract:
The concentration levels of six heavy metals (Cd, Cr, Fe, Ni, Pb and Zn) and two mineral elements (Ca and Mg) were determined in soil samples collected from the vicinity of two auto mechanic workshops in Sabon-Gari, Kaduna state, Nigeria, using Atomic Absorption Spectrometry (AAS), in order to compare the gradation of their concentrations with distance and depth of soil from the workshop sites. At site 1, concentrations of Lead, Chromium, Iron and Zinc were generally found to be above the World Health Organization limits, while those of Nickel and Cadmium fell within the limits. Iron had the highest concentration with a range of 176.274 ppm to 489.127 ppm at depths of 5 cm to 15 cm and a distance range of 5 m to 15 m, while the concentration of cadmium was least with a range of 0.001 ppm to 0.008 ppm at similar depth and distance ranges. In addition, there was more of calcium (11.521 ppm to 121.709 ppm), in all the samples, than magnesium (11.293 ppm to 21.635 ppm). Similar results were obtained for site II. The concentrations of all the metals analyzed showed a downward gradient with increase in depth and distance from both workshop sites except for iron and zinc at site 2. The immediate and remote implications of these findings on the biota are discussed.
Keywords: AAS, Heavy Metals, Mechanic Workshops, Soils.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1099494
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[1] Duruibe, J. O., Ogwuegbu, M. O. C. and Egwurugwu, J. N. (2007). Heavy metal pollution and human bio toxic effects. International Journal of Physical Sciences. Vol.2, Pp. 112-118
[2] Marcovecchio, J. E., Botte, S. E., and Freije,R. H.(2007). Heavy metals, Major Metals, Trace Elements.Handbook of water analysis,2nd edition. London, CRC Press, Pp. 275-311
[3] Manaham, S. E. (2005). Environnmental chemistry. 8th edition, lewis publisher, Boca Raton, Florida
[4] Muchuweti, M., Birtkett, J. W., Chinyanga, E., Zvauya,R., Scrimshaw M.D. and Lester, J.N. (2006).Heavy metal content of vegetables irrigated with mixture of waste water and sewage sludge in Zimbabwe:Implications for human health.Agricultural Ecosystem Environnmental, Vol.112, Pp.41-48.
[5] Wilson, B. And Pyatt, F. B. (2007).Heavy metal dispersion, persistence, and bioaccumulation around an ancient copper mine situated in A nglessy. Ecotoxicology Environmental safety ,Vol.66,Pp. 224-231
[6] Mahjoobi A., Albaji, M, and Torfi, K. (2010). Determination of heavy metal levels of kondok soils-halftgel. Research. Journal of environnemental science. Vol. 4, Pp. 294-299
[7] McMurry, J. And R. C. Fay, 2004. Hydrogen, oxygen and water. McMurry Fay Chemist, 4th Edn.New Jersey: Pearson Education, Pp. 575-599
[8] Paul E.D., Gimba C.E., Kagbu J.A., Ndukwe G.I. and Okibe F.G (2011). Spectrometric Determination of Fluoride in Water, Soil and Vegetables from the Precinct of River Basawa, Zaria, Nigeria J. Basic. Appl. Chem., 1(6)33-38
[9] Jones, R. R. (1989). The Continuing hazard of lead in drinking water. Lancet 16. Pp. 669-670.