F. Amireche

Abstracts

2 Volumetric Properties of Binary Mixtures of Glycerol +1-Butanol or +2-Butanol at Several Temperatures

Authors: F. Amireche, Y. Chabouni

Abstract:

Densities of glycerol + 1-butanol or 2-butanol mixtures were measured over the temperature range 293.15 to 303.15 K at atmospheric pressure, over the entire composition range, with a vibrating tube densimeter. Excess molar volumes, apparent and partial molar volumes of glycerol and butanol, thermal isobaric expansivities of the mixture and partial molar expansivities of the components were calculated. The excess molar volumes of the mixtures are negative at all temperatures, and deviations from ideality increase with increasing temperature. Excess molar volumes were fitted to the Redlich–Kister equation. Partial molar volumes of glycerol decrease with increasing butanol concentration.

Keywords: Density, glycerol, excess molar volume, partial molar property, thermal isobaric expansivities

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1 Thermodynamic Properties of Binary Mixtures of 1, 2-Dichloroethane with Some Polyethers: DISQUAC Calculations Compared with Dortmund UNIFAC Results

Authors: F. Amireche, I. Mokbel, J. Jose, B. F. Belaribi

Abstract:

The experimental vapour-liquid equilibria (VLE) at isothermal conditions and excess molar Gibbs energies GE are carried out for the three binary mixtures: 1, 2- dichloroethane + ethylene glycol dimethyl ether, + diethylene glycol dimethyl ether or + diethylene glycol diethyl ether, at ten temperatures ranging from 273 to 353.15 K. A good static device was employed for these measurements. The VLE data were reduced using the Redlich-Kister equation by taking into consideration the vapour pressure non-ideality in terms of the second molar virial coefficient. The experimental data were compared to the results predicted with the DISQUAC and Dortmund UNIFAC group contribution models for the total pressures P, the excess molar Gibbs energies GE and the excess molar enthalpies HE.

Keywords: Disquac model, Dortmund UNIFAC model, excess molar Gibbs energies GE, polyethers, VLE

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