{"title":"Synthesis and Use of Thiourea Derivative (1-Phenyl-3- Benzoyl-2-Thiourea) for Extraction of Cadmium Ion","authors":"Abdulfattah M. Alkherraz, Zaineb I. Lusta, Ahmed E. Zubi ","volume":86,"journal":"International Journal of Environmental and Ecological Engineering","pagesStart":108,"pagesEnd":111,"ISSN":"1307-6892","URL":"https:\/\/publications.waset.org\/pdf\/9997379","abstract":"
The environmental pollution by heavy metals became
\r\nmore problematic nowadays. To solve the problem of Cadmium
\r\naccumulation in human organs which lead to dangerous effects on
\r\nhuman health, and to determine its concentration, the organic legand
\r\n1-phenyl-3-benzoyl-2-thiourea was used to extract the cadmium ions
\r\nfrom its solution. This legand as one of thiourea derivatives was
\r\nsuccessfully synthesized. The legand was characterized by NMR and
\r\nCHN elemental analysis, and used to extract the cadmium from its
\r\nsolutions by formation of a stable complex at neutral pH. The
\r\ncomplex was characterized by elemental analysis and melting point.
\r\nThe concentrations of cadmium ions before and after the extraction
\r\nwere determined by Atomic Absorption Spectrophotometer (AAS).
\r\nThe data show the percentage of the extract was more than 98.7% of
\r\nthe concentration of cadmium used in the study<\/p>\r\n","references":"J. Gilbert, 1984. Analysis of food contamination. Elsevier App. Sci. \r\nPups., London 1. \r\n[2] S. Edrah, J. Appl. Scien. R, 2010, 4(8): 1014-1018. \r\n[3] W. Rabb, J. Appl. Cosmetol, 1997, 15(4): 115-123. \r\n[4] C. Alkan, Y. Tek and D. Kahraman, Turk J Chem, 2011, 35, 769 \u2013 777. \r\n[5] M. Kodomari, M. Suzuki, K. Tanigawa and T. Aoyama, Tetrahedron \r\nLett, 2005, 46, 5841. \r\n[6] J. S. Ren, J. Diprose, J. Warren, R.M. Esnouf, L.E. Bird, S. Ikemizu, M. \r\nSlater, J. Milton, J. Balzarini, D.L. Stuart and D.K. Stammers, J Biol \r\nChem 2000, 275, 5633. \r\n[7] F. T. Elmali, U. Avciata and N. Demirhan, Main Group Chemistry 2011, \r\n10: 17\u201323 \r\n[8] A. R. Katritzky and M. F. Gordeev, J. Chem. Soc., Perkin 1991, 1: 2199-\r\n2203. \r\n[9] M. Struga, J. Kossakowski, E. Kedzierska, S. Fidecka, and J. Stefanska, \r\nChem. Pharm. Bull, 2007, 55(5): 796-799. \r\n[10] A. D. Desai, D. H. Mahajan, and K. H. Chikhalia, Ind. J. of Chem., \r\n2007, 46B: 1169-1173. \r\n[11] R. B. Patel, K. H. Chikhalia, C. Pannecouque, and E. D. Clercq, J. Braz. \r\nChem. Soc., 2007, 18(2): 312-321. \r\n[12] G. A. Kilcigil, and N. Altanlar, Turk J. Chem., 2006, 30: 223-228. \r\n[13] S. Xue, J. Shan Zou, and H. Yong, Chin. Chem. Letters, 2000, 11(1), 19-\r\n20. \r\n[14] C. Fengling, C. Yanrui, L. Hongxia, Y. Xiaojun, F. Jing, and L. Yan, \r\nChinese Science Bulletin, 2006, 51(18): 2201-2207. \r\n[15] K. R. Koch, Coord. Chem. Rev., 2001, vol. 216-217, pp. 473\u2013488,. \r\n[16] S. Saeed, N. Rashid, M. H. Bhatti, and P. G. Jones, Turk J. Chem., 2010, \r\n34(5),761\u2013770. \r\n[17] H. Arslan, U. Florke, N. Kulcu, and E. Kayhan, Turk J. Chem., 2006, 30: \r\n429-440. \r\n[18] G. Avsar, H. Arslan, H. J. Haupt, and N. Kulcu, Turk J. Chem., 2003, \r\n27: 281-285. \r\n[19] H. Arsalan, and N. kuku, Transition metal Chemistry, 2003, 28: 816-\r\n819. \r\n[20] B. H. Abdullah and Y. M. Salh, Oriental J. Chem., 2010, 26(3), 763-\r\n773. \r\n[21] C. W. Sun and X. D. Zhang, Chin. J. Struc. Chem., 2007, 26(2), 153\u2013\r\n156. \r\n[22] A. Saeed, R. A. Khera, N. Abbas, M. Latif, I. Sajid, and U. Fl\u00f6rke, Turk \r\nJ. Chem., 2010, 34(3), 335\u2013345,. \r\n[23] S. Saeed, N. Rashid, M. Ali, and R. Hussain, Europ. J. Chem., 2010, \r\n1(3), 200\u2013205. \r\n[24] M. Eweis, S. S. Elkholy, and M. Z. Elsabee, Inter. J. Biol. Macromolec, \r\n2006, 38(1), 1\u20138. \r\n[25] D. Sriram, P. Yogeeswari, M. Dinakaran, and R. irumurugan, Journal of \r\nAntimicrobial Chemotherapy, 2007, 59(6), 1194\u20131196. \r\n[26] B. K. Kaymakcioglu, S. Rollas, and F. Kartal-Aricioglu, Europ. J. Drug \r\nMetabo. and Pharmacokinetics, 2003, 28(4), 273\u2013278,. \r\n[27] M. G. Soung, K. Y. Park, J. H. Song, and N. D. Sung, J. Kore. Soc. \r\nAppl. Biolo. Chem., 2008, 51(3), 219\u2013222. \r\n[28] A. Saeed and M. Batool, Medic. Chem. Res., 2007, 16(3), 143\u2013154. \r\n[29] S. Saeed, N. Rashid, M. Ali, R. Hussain, and P. G. Jones, Europ. J. \r\nChem., 2010, 1(3), 221\u2013227. \r\n[30] D. K. Das, Fres. J. Anal. Chem., 1984, 318(8), 612. \r\n[31] S. C. Shome, M. Mazumdar, and P. K. Haldar, J. Ind. Chem. Soc., 1980, \r\n57(2), 139\u2013141. \r\n[32] G. Binzet, B. Zeybek, E. K\u0131l\u0131\u00e7, N. K\u00fclc\u00fc, and H. Arslan, J. Chem., 2013, \r\n7 pages. \r\n[33] A. Hakan, K. Nevzat, F. Ulrich. Spectrochimica Acta, 2006, Part A 64, \r\n1065. \r\n[34] O. A. Hassan, A. M. Otaiwi and A. Abeer, Natio. J. Chem., 2008: 31, \r\n501-513. \r\n[35] H. Arslan, N. Duran, G. Borekci, C. K. Ozer, and C. Akbay, Molecul., \r\n2009, 14: 519-527. \r\n[36] H. A. Dondas, Y. Nural, N. Duran, and C. Kilner, Turk J. Chem., 2006, \r\n30: 573-583. \r\n[37] M. S. Rathod and S. Z. Jadhao, J. Chem. and Pharm. Res., 2012, 4(3), \r\n1629-1631. \r\n[38] W. Henderson, B. K. Nicholson, and C. E. F. Rickard, Inorg. Chim. \r\nActa, 2001, 320: 101- 109. \r\n[39] C. D. Badiceanu, C. Draghici and A. Missir Rev. Roum. Chim., 2010, \r\n55(6), 307-311 \r\n[40] G. Y. Sarkis and E. D. Faisal, J. Heteerocyclic chem., 1985, 22, 137.","publisher":"World Academy of Science, Engineering and Technology","index":"Open Science Index 86, 2014"}