WASET
	%0 Journal Article
	%A H. Hosseini and  M. Javadi and  M. Moghiman and  M. H. Ghodsi Rad
	%D 2010
	%J International Journal of Chemical and Molecular Engineering
	%B World Academy of Science, Engineering and Technology
	%I Open Science Index 38, 2010
	%T Carbon Disulfide Production via Hydrogen Sulfide Methane Reformation
	%U https://publications.waset.org/pdf/7418
	%V 38
	%X Carbon disulfide is widely used for the production of
viscose rayon, rubber, and other organic materials and it is a
feedstock for the synthesis of sulfuric acid. The objective of this
paper is to analyze possibilities for efficient production of CS2 from
sour natural gas reformation (H2SMR) (2H2S+CH4 =CS2 +4H2) .
Also, the effect of H2S to CH4 feed ratio and reaction temperature on
carbon disulfide production is investigated numerically in a
reforming reactor. The chemical reaction model is based on an
assumed Probability Density Function (PDF) parameterized by the
mean and variance of mixture fraction and β-PDF shape. The results
show that the major factors influencing CS2 production are reactor
temperature. The yield of carbon disulfide increases with increasing
H2S to CH4 feed gas ratio (H2S/CH4≤4). Also the yield of C(s)
increases with increasing temperature until the temperature reaches
to 1000°K, and then due to increase of CS2 production and
consumption of C(s), yield of C(s) drops with further increase in the
temperature. The predicted CH4 and H2S conversion and yield of
carbon disulfide are in good agreement with result of Huang and TRaissi.
	%P 198 - 201