@article{(Open Science Index):https://publications.waset.org/pdf/7364,
	  title     = {Determination of Chemical Oxygen Demand in Spent Caustic by Potentiometric Determination},
	  author    = {Hamed Harrafi and  Masoumeh Khedri and  Karim Karaminejad},
	  country	= {},
	  institution	= {},
	  abstract     = {Measurement of the COD of a spent caustic solution involves firstly digestion of a test sample with dichromate solution and secondly measurement of dichromate remained by titration by ferrous ammonium sulfate [FAS] to an end point. In this paper we study by a potentiometric end point with Ag/AgCl reference electrode and gold rode electrode. The potentiometric end point is sharp and easily identified especially for the samples with high turbidity and color that other methods such as colorimetric in this type of sample do not result in high precision. Because interim of titration responds quickly to potential changes within the [Cr+6/Cr+3& Fe+2/Fe+3] solution producing stable readings that is lead to accurate COD measurement. Finally results are compared with data determined using colorimetric method for standard samples. It is shown that the potentiometric end point titration with gold rode electrode can be used with equal or better facility
},
	    journal   = {International Journal of Chemical and Molecular Engineering},
	  volume    = {6},
	  number    = {7},
	  year      = {2012},
	  pages     = {559 - 561},
	  ee        = {https://publications.waset.org/pdf/7364},
	  url   	= {https://publications.waset.org/vol/67},
	  bibsource = {https://publications.waset.org/},
	  issn  	= {eISSN: 1307-6892},
	  publisher = {World Academy of Science, Engineering and Technology},
	  index 	= {Open Science Index 67, 2012},
	}