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Wine Grape Residues Gasification in Supercritical Water

Authors: D. Selvi Gökkaya, M. Yüksel, M. Sağlam, T. Güngören Madenoğlu, N. Cengiz, T. Çokkuvvetli, L. Ballice

Abstract:

In this study, production possibilities of hydrogen and/or methane via SCWG from black grape residues have been investigated. For this aim, grape residues which remain as a byproduct of the wine making process have been used. Since utilization from grape residues is limited due to the high moisture content, supercritical water gasification is the most convenient method. The effect of the gasification temperature and type of catalyst on supercritical water gasification have been investigated. Gasification experiments were performed in a batch autoclave at four different temperatures 300, 400, 500 and 600°C. K2CO3 and Trona (NaHCO3.Na2CO3·2H2O) were used as catalyst. Real biomass types of black grape residues have been successfully gasified and the product gas (hydrogen, methane, carbon dioxide, carbon monoxide and a small amount of ethane and ethylene) were identified by using gas chromatography. A TOC analyzer was used to determine total organic carbon (TOC) content of aqueous phase. The amounts of carboxylic acids, aldehydes, ketones, furfurals and phenols present in the aqueous solutions were analyzed by high performance liquid chromatography. When the temperature increased from 300°C to 600°C, mol% of H2 in gas products increased. The presence of catalysts improves the hydrogen yield. Trona showed gasification activity to be similar to that of K2CO3. It may be concluded that the use of Trona instead of commercially produced catalysts, can be preferably used in the gasification of biomass in supercritical water.

Keywords: Biomass, hydrogen, grape residues.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1331125

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References:


[1] N. Boukis. U. Galla. H. M├╝ller. E. Dinjus. "Biomass Gasification in Supercritical Water. Experimental progress achieved with the verana pilot plant". 15th European Biomass Conferance&Exhibition.Berlin Germany. 7-11 May 2007.
[2] A. Hammerschmidt. N. Boukis . E. Hauer. U. Galla . E. Dinjus. B. Hitzmann . T. Larsen . S. D. Nygaard. "Catalytic conversion of waste biomass by hydrothermal treatment". Fuel. 2011. 90. pp.555-562.
[3] T. L.-Kelly Yong. Y. Matsumura. "Catalytic Gasification of Poultry Manure and Eucalyptus Wood Mixture in Supercritical Water". Ind. Eng. Chem. Res.. 2012. 51. pp.5685−5690.
[4] A. Loppinet-Serani. C. Reverte. F. Cansell. C. Aymonier. "Supercritical Water Biomass Gasification Process As a Successful Solution to Valorize Wine Distillery Wastewaters". ACS Sustainable Chem. Eng.. 2013. 1. pp.110−117
[5] K. Ayd─▒ncak. T. Yumak. A. Sinag. B. Esen. "Synthesis and Characterization of Carbonaceous Materials from Saccharides (Glucose and Lactose) and Two Waste Biomasses by Hydrothermal Carbonization". Ind. Eng. Chem. Res.. 2012. 51. pp.9145−9152.
[6] P. Azadi. K.M. Syed. R. Farnood . "Catalytic gasification of biomass model compound in near-critical water". Applied Catalysis A: General 358. 2009.pp. 65-72.
[7] P. Azadi. R. Farnood. "Review of heterogeneous catalysts for sub- and supercritical water gasification of biomass and wastes. International J. of hyfrohen energy. 2011. 36. pp.9529-9554.
[8] M. H. Waldner . F. Krumeich . F. Vogel. "Synthetic natural gas by hydrothermal gasification of biomass Selection procedure towards a stable catalyst and its sodium sulfate tolerance". J. of Supercritical Fluids. 2007. pp. 4391-105
[9] H. Pinkowska. P. Wolak. A. Z1ocinska. "Hydrothermal decomposition of xylan as a model substance for plant biomass waste-Hydrothermolysis in subcritical water". Biomass and Boenergy 2011. 35. pp. 3902-3912
[10] Ekin K─▒pcak. Onur O. Sogut. Mesut Akgun.Hydrothermal gasification of olive mill wastewater as a biomass source in Supercritical water. J. of Supercritical Fluids 57 (2011) 50-57
[11] M.B. Garcia Jarana. J. S. Oneto. J.R. Portela. E. N. Sanz. E.J. Martinez de la Ossa. "Supercritical water gasification of industrial organic wastes". J. of Supercritical Fluids. 2008.46. pp.329-334.
[12] Y. Matsumura. T. Minowa. B. Potic. S. R. A. Kersten. P.M Willibrordus. B. Beld. D.Elliott. G. Neuenschwander. A. Kruse. M. Antal. "Biomass gasification in near-and super-critical water: status and prospects". Biomass and Bioenergy. 2005. 29. pp.269-292.
[13] Y. Calzavara. C. Joussot-Dubien. G. Boissonnet. S. Sarrade. "Evaluation of biomass gasification in supercritical water process for hydrogen production". Energy Conversion Management. 2005. 46. pp.615-631.
[14] A. Loppinet-Serani. C. Aymonier. F. Cansell."Current and foreseeable applications of supercritical water for energy and the environment". Chem.Sus.Chem.. 2008. 1. pp.486-503. A.A. Peterson. F. Vogel. R.P. Lachance. M. Fröling. M.J Jr. Antal. J. Tester. "Thermochemical biofuel production in hydrothermal media: a review of sub- and supercritical water technologies". Energy and Environmental Science. 2008. 1. pp.32-65.
[15] A. Kruse. "Supercritical water gasification". Biofuels Bioproducts & Biorefining 2008. 2. pp.415-437.
[16] P."Basu. V. Mettanant. "Biomass gasification in supercritical water-a review". International J. Chemical Reaction Engineering. 2009. 7. Review R3.
[17] R.M. Navarro. M.C. Sánchez. M.C. Alvarez-Galvan. F. del Valle. J. L. G. Fierro." Hydrogen production from renewable sources: biomass and photocatalytic". Energy and Environmental Science. 2009. 2. pp.35-54.
[18] Y. Guo. S.Z. Wang. D.H. Xu. Y.M. Gong. H.H. Ma. X.Y. Tang. "Review of catalytic supercritical water gasification for hydrogen production from biomass". Renewable Sustainable Energy. 2010.14. p.334.
[19] T.A. Mitsuru Sasaki. K. Arai. "Kinetics of cellulose conversion at 25 MPa in sub and supercritical water". AIChE J.. 2004. 50. pp. 192-202.
[20] B.M. Kabyemela. M. Takigawa. T. Adschiri. R.M. Malaluan. K. Arai. "Mechanism and kinetics of cellobiose decomposition in sub- and supercritical water". Industrial and Engineering Chemistry Research. 1998. 37. pp.357-361.
[21] P.T. Williams. J. Onwudili. "Composition of products from the supercritical water gasification of glucose: a model biomass compound". Industrial and Engineering Chemistry Research. 2005. 44. pp. 8739- 8749.
[22] A. Sinag. A. Kruse. V. Schwarzkopf. "Key compounds of the hydropyrolysis of glucose in supercritical water in the presence of K2CO3". Industrial and Engineering Chemistry Research. 2003. 42. pp. 3516-3521.
[23] Z. Fang. T. Sato. L.R. Smith Jr.. H. Inomata. K. Arai. J.A. Kozinski. "Reaction chemistry and phase behavior of lignin in high-temperature and supercritical water". Bioresource Technology. 2008. 99. pp. 3424- 3430
[24] H.K. Goering. P.J. Van Soest. "Forage fiber analysis in: Agriculture Handbook". Superintendent of Documents. US Government Printing Office. Washington. DC. 1970. pp. 829-835.
[25] T. Gungoren. M. Saglam. M. Yuksel. H. Madenoglu. R. Isler. I.H. Metecan. A.R. Ozkan. L. Ballice. "Near-critical and supercritical fluid extraction of industrial sewage sludge". Industrial and Engineering Chemistry Research. 2007. 46. pp.1051-1057.
[26] R. F. Nascimento. .J. C. Marques.; B. S. L. Neto. D. D. Keukeleire. D. W. Franco. "Qualitative and quantitative high-performance liquid chromatographic analysis of aldehydes in Brazilian sugar cane spirits and other distilled alcoholic beverages". J. Chromatogr A. 1997. pp.782. 13.
[27] J. Yanik.; S. Ebale. A.Kruse.; M.Saglam. M.Yuksel. "Biomass gasification in supercritical water: II". Effect of catalyst.. Int. J. Hyd. Energy. 2008. 33. pp. 4520-4526
[28] A. Sinag. A. Kruse. V. Schwarzkopf. "Key compounds of the hydropyrolysis of glucose in supercritical water in the presence of K2CO3". Ind. Eng. Chem. Res.. 2003. 42. p. 3516.
[29] A. Kruse. E. Dinjus. "Influence of salts during hydrothermal biomass gasification: the role of the catalysed water-gas shift reaction". Zeitschrift fur Physikalische Chemie: Neue Folge. 2005. pp.219-341.
[30] T. Minowa. T. Ogi. S. Yokoyama. "Hydrogen Production from Wet Cellulose by Low-Temperature Gasification Using a Reduced Nickel Catalyst". Chem. Lett.. 1995. p.937.
[31] J. Yu. P. E. Savage. "Decomposition of Formic Acid under Hydrothermal Conditions". Ind. Eng. Chem. Res.. 1998. 37.
[32] M . Watanabe. T. Sato. I. Hnomata.; R. L. Jr. Smith. K. Arai. A. Kruse. E. Dinjus. "Chemical Reactions of C1 Compounds in Near-Critical and Supercritical Water". Chem. Rev. 2004. 104. 5803-582.