Methanol Concentration Sensitive SWCNT/Nafion Composites
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32799
Methanol Concentration Sensitive SWCNT/Nafion Composites

Authors: Kyongsoo Lee, , Seong-Il Kim, Byeong-Kwon Ju

Abstract:

An aqueous methanol sensor for use in direct methanol fuel cells (DMFCs) applications is demonstrated; the methanol sensor is built using dispersed single-walled carbon nanotubes (SWCNTs) with Nafion117 solution to detect the methanol concentration in water. The study is aimed at the potential use of the carbon nanotubes array as a methanol sensor for direct methanol fuel cells (DMFCs). The concentration of methanol in the fuel circulation loop of a DMFC system is an important operating parameter, because it determines the electrical performance and efficiency of the fuel cell system. The sensor is also operative even at ambient temperatures and responds quickly to changes in the concentration levels of the methanol. Such a sensor can be easily incorporated into the methanol fuel solution flow loop in the DMFC system.

Keywords: methanol concentration, SWCNT, nafion composites

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1330075

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1887

References:


[1] G. O. Young, "Synthetic structure of industrial plastics (Book style with paper title and editor)," in Plastics, 2nd ed. vol. 3, J. Peters, Ed. New York: McGraw-Hill, 1964, pp. 15-64.
[2] Kimberly M. McGrath, G.K.Surya Prakash and George.A.Olah, Journal of Industrial and Engineering Chemistry, Direct Methanol Fuel Cells, 10, (2004) 1036-1080.
[3] B.Ilic, P.Neuzil, T.Stanczyk, D.Czaplewski and G.Jordan Maclay, Electrochemical and Solid-State Letters, Low temperature Nafion bonding of silicon wafer, 2, (1999) 86-87.
[4] E.Skou, P.Kauranen and J. Hentschel, Solid State Ionics, Water and methanol uptake in proton conducting Nafion membrane, 97, (1997) 333-337.
[5] X.Ren, T.E.Springer and S.Gottesfeld, Journal of The Electrochemical Society, Water and metahnol Uptakes in Nafion Membranes and membrane effect on direct methanol cell perfomance, 147, (2000) 92-98.
[6] Kenneth A. Mauritz, Rovert B. Moore, Chemical Reviews, State of understanding of Nafion, 104, (2004) 4535.
[7] K. Ramya, K.S. Dhathathreyan, Journal of Electroanalytical Chemistry, Direct methanol fuel cell : determination of fuel crossover in a polymer electrolyte membrane, 542, (2003) 109- 115.
[8] A.Heinzel, V.M.Barragan, Journal of Power Sources, A review of the state-of-the-art of the methanol crossover in direct methanol fuel cell, 84, (1999) 70-74.