Sorption of Nickel by Hypnea Valentiae: Application of Response Surface Methodology
Commenced in January 2007
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Sorption of Nickel by Hypnea Valentiae: Application of Response Surface Methodology

Authors: M. Rajasimman, K. Murugaiyan

Abstract:

In this work, sorption of nickel from aqueous solution on hypnea valentiae, red macro algae, was investigated. Batch experiments have been carried out to find the effect of various parameters such as pH, temperature, sorbent dosage, metal concentration and contact time on the sorption of nickel using hypnea valentiae. Response surface methodology (RSM) is employed to optimize the process parameters. Based on the central composite design, quadratic model was developed to correlate the process variables to the response. The most influential factor on each experimental design response was identified from the analysis of variance (ANOVA). The optimum conditions for the sorption of nickel were found to be: pH – 5.1, temperature – 36.8oC, sorbent dosage – 5.1 g/L, metal concentration – 100 mg/L and contact time – 30 min. At these optimized conditions the maximum removal of nickel was found to be 91.97%. A coefficient of determination R2 value 0.9548 shows the fitness of response surface methodology in this work.

Keywords: Optimization, metal, Hypnea valentia, response surface methodology, red algae.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1085589

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References:


[1] Y. H. Kim, J. Y. Park, Y. J. Yoo, and J. W. Kwak, "Removal of lead using xanthated marine brown algae, Undaria Pinnatifida", Process Biochemistry, vol. 34, 1999, pp. 647-652.
[2] C. J. Tien, "Biosorption of metal ions by freshwater algae with different surface characteristics", Process Biochemistry, vol.38, 2002, pp. 605 - /613.
[3] P. Kaewsarn, "Biosorption of copper (II) from aqueous solutions by pretreated biomass of marine algae Padina sp.", Chemosphere, vol.47, 2002, pp. 1081-1085.
[4] P. A. Terry, and W. Stone, "Biosorption of cadmium and copper contaminated water by Scenedesmus abundans", Chemosphere, vol.47, 2002, pp.249-255.
[5] R. Jalali, H. Ghafourian, Y. Asef, S. J. Davarpanah, and S. Sepehr, "Removal and recovery of lead using nonliving biomass of marine algae", Journal of Hazardous Materials, vol. B92, 2002, pp. 253-262.
[6] Y. Prasanna Kumar, P. King, and P.S.R.K Prasad, "Adsorption of zinc from aqueous solution using marine green algaeÔÇöUlva fasciata sp." Chemical Engineering Journal, vol.129, 2007, pp. 161-166.
[7] L. Denga, Y. Sua, H. Sua, X. Wang, and X. Zhua, X., "Sorption and desorption of lead (II) from wastewater by green algae Cladophora fascicularis", Journal of Hazardous Materials, vol.143, 2007, pp. 220- 225.
[8] A. Ozera, G. Gurbuza, A. C. Alimli, and B. K. Korbahtia, "Biosorption of copper (II) ions on Enteromorpha prolifera: Application of response surface methodology", Chemical Engineering Journal, vol. 146, 2009, pp. 377-387.
[9] K. Ravikumar, K. Pakshirajan, T. Swaminathan, and K. Balu, "Optimization of batch process parameters using response surface methodology for dye removal by a novel adsorbent" Chemical Engineering Journal, vol. 105, 2005, pp. 131-138.
[10] B. K. Korbahti, "Response surface optimization of electrochemical treatment of textile dye wastewater", Journal of Hazardous Materials, vol. 145, 2007, pp. 277-286.
[11] A. Aleboyeh, N. Daneshvar, and M.B. Kasiri, "Optimization of C.I. Acid Red 14 azo dye removal by electrocoagulation batch process with response surface methodology", Chemical Engineering and Processing, vol.47, 2008, pp. 827-832.
[12] U. K. Garg, M. P. Kaur, V. K. Garg, and D. Sud, "Removal of Nickel (II) from aqueous solution by adsorption on agricultural waste biomass using a response surface methodological approach", Bioresource Technology, vol.99, 2008, pp. 1325-1331.
[13] P. Manivannan, and M. Rajasimman, "Optimization of osmotic dehydration of radish in sugar solution", International journal of Chemical and Biomolecular Engineering, vol.1 (4), 2008, pp. 215-222.
[14] M. Rajasimman, and S. Subathra, "Optimization of gentamicin production: Comparison of RSM and ANN techniques", International journal of Chemical and Biomolecular Engineering, vol. 2 (1), 2009, pp. 14 -19.
[15] M. Rajasimman, and S. Subathra, "Process Parameter Optimization for the Production of Gentamicin using Micromonouspora Echiniospora", International journal of Chemical and Biomolecular Engineering, vol. 3 (1), 2010, pp. 29-32.
[16] R. Rajeshkannan, N. Rajamohan, and M. Rajasimman, "Removal of malachite green from aqueous solution by sorption on hydrilla verticillata biomass using response surface methodology", Frontiers of Chemical Engineering China, vol. 3, 2009, pp. 146-154.
[17] Y. S. Yun, D. Park, J. M. Park, and B. Volesky, "Biosorption of trivalent chromium on the brown seaweed biomass", Environ. Sci. Technol., vol. 35, 2001, pp. 4353-4358.
[18] M. Saleem, T. Pirzada, and R. Qadeer, "Sorption of acid violet 17 and direct red 80 dyes on cotton fiber from aqueous solutions", Colloids Surf. A: Physicochem. Eng. Asp., vol. 292, 2007, pp. 246-250.
[19] L. Khezami, and R. Capart, "Removal of chromium(VI) from aqueous solution by activated carbons: kinetic and equilibrium studies", Journal of Hazardous Materials, vol 123, 2005, pp. 223 - 231.
[20] S. K. Das, and A. K. Guha, "Biosorption of chromium by Termitomyces clypeatus", Colloid Surf. Vol.B60, 2007, pp. 46-54.