Influence of Reaction Temperature and Water Content on Wheat Straw Pyrolysis
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Influence of Reaction Temperature and Water Content on Wheat Straw Pyrolysis

Authors: N.Ibrahim, Peter A. Jensen, K. Dam-Johansen, Roshafima.R. Ali, Rafiziana.M. Kasmani

Abstract:

The aim of this study was to investigate the influence of reaction temperature and wheat straw moisture content on the pyrolysis product yields, in the temperature range of 475-575 °C. Samples of straw with moisture contents from 1.5 wt % to 15.0 wt % were fed to a bench scale Pyrolysis Centrifuge Reactor (PCR). The experimental results show that the changes in straw moisture content have no significant effect on the distribution of pyrolysis product yields. The maximum bio-oil yields approximately 60 (wt %, on dry ash free feedstock basis) was observed around 525 °C - 550 °C for all straw moisture levels. The water content in the wet straw bio-oil was the highest. The heating value of bio-oil and solid char were measured and the percentages of its energy distribution were calculated. The energy distributions of bio-oil, char and gas were 56- 69 % 24-33 %, and 2-19 %, respectively.

Keywords: Flash pyrolysis, moisture content, wheat straw, biooil.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1082799

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References:


[1] K. Sipila, E. Kuoppala, L. Fagernae`s, "Characterization of biomass- based flash pyrolysis oils," Biomass and Bioenergy., vol. 14, pp. 103- 13, 1998.
[2] A.E. Putun, "Biomass to bio-oil via fast pyrolysis of cotton straw and stalk," Energy Sources, vol. 24, pp. 275-85, 2002.
[3] C. Acikgoz, A.M. Kockar, "Flash pyrolysis of Linseed (Linum usitatissimum L.) For production of liquid fuels," Journal of Analytical and Applied Pyrolysis., vol. 78, pp. 406-12, 2007.
[4] D. Mohan, U. Charles, J. Pittman, H.S. Philip, "Pyrolysis of wood/biomass for bio-oil: Critical Review," Energy & Fuels., vol. 20, pp. 848-89, 2006.
[5] IEA-International Energy Agency (2006), http://www.ieabioenergy.com
[6] J.L. Gaunt, L. Lehmann, "Energy balance and emissions associated with biochar sequestration and pyrolysis bioenergy production," Environ.Sci.Techno., vol. 42, pp. 4152-4158, 2008.
[7] J.A. Mathews, "Carbon-negative biofuels," Energy Policy, vol. 26, pp. 940-945, 2008.
[8] M.E. Sanchez, E. Lindao, D. Margaleff, O. Martinez, A. Maron," Pyrolysis of agricultural residues from rape and sunflowers: production and characterization of bio-fuels and biochar soil management," J.Ana.Appl.Pyrolysis., vol. 85, pp. 142-144, 2009.
[9] J.L. Zheng, "Bio-oil from fast pyrolysis of rice husk: yields and related properties and improvement of the pyrolysis system," J.Ana.Appl.Pyrolysis., vol. 80, pp. 30-35, 2007.
[10] A.V. Bridgwater, G.V.C. Peacocke,"Fast pyrolysis process for biomass," Renewable & Sustainable Energy Reviews, vol. 4, pp. 1-73, 2000.
[11] N. Bech, PhD Thesis 2008: "In situ flash pyrolysis of straw," Technical University of Denmark, Denmark.
[12] N, Bech, M.B. Larsen, P.A. Jensen, K. Dam-Johansen, "Modelling solid-convective flash pyrolysis of straw and wood in the pyrolysis centrifuge reactor," Biomass and Bioenergy., vol. 33, pp. 999-1011, 2009.
[13] M.J. Antal, "Effects of reactor severity on the gas-phase pyrolysis of cellulose- and kraft lignin-derived volatile matter," Ind Eng Prod Res Dev., vol. 22, pp. 366-375, 1983.
[14] M.J. Antal, A review of the vapor phase pyrolysis of biomass derived volatile matter. In: Overend RP, Milne TA, Mudge LK, editors. Fundamentals of biomass thermochemical conversion, London: Elsevier; 1985, p. 511-37.
[15] A.V. Bridgwater, "Catalysis in thermal biomass conversion," Applied Catalysis., vol. 116, pp. 5-47, 1994.
[16] M.R. Gray, W.H. Corcoran, G.R. Gavalas, "Pyrolysis of a wood - derived material: Effect of moisture and ash content," Ind.Eng.Chem. Process Des.,Vol. 24, pp. 646-651.
[17] F. Shafizadeh, "Pyrolysis and combustion of cellulose materials," Adv.Carbohydr.Chem., vol. 23, pp. 419, 1968.
[18] R.J.M. Westerhof, N.J.M. Kuipers, S.R.A. Kersten and W.P.M. Van Swaaij, "Controlling the water content of biomass fast pyrolysis oil," Ind.Eng.Chem.Res., vol. 46, pp. 9238-9247, 2007.
[19] A. Demirbas, "Effect of initial moisture content on the yields of oily products from pyrolysis of biomass," Journal of Analytical and Applied Pyrolysis., vol. 71, pp. 803-815, 2004.
[20] N. Bech, K. Dam-Johansen and P.A. Jensen, "Pyrolysis method and apparatus," PCT Application. WO 2006/117005, 2006.
[21] N. Bech, P.A. Jensen and K. Dam-Johansen, "Ablative flash pyrolysis of straw and wood: Bench- scale results," Proc 15th European Biomass Conference and Exhibition, Berlin, 7-11 May 2007.
[22] K. Raveendran, A. Ganesh, "Heating value of biomass and biomass pyrolysis products,"Fuel., vol. 75, pp. 1715-1720, 1996.
[23] M. Balat, "Mechanism of thermochemical biomass conversion processes. Part 1: Reactions of pyrolysis," Energy Sources., vol. 30, pp. 620-635, 2008.
[24] A.V. Bridgwater, "Biomass fast pyrolysis process for biomass," Thermal Science., vol. 8, pp. 21-49, 2004.
[25] D. Elliott, "Water, alkali and char in flash pyrolysis oils," Biomass and Bioenergy., vol. 7, pp. 179-185, 1994.
[26] Y.K. Park, J.K. Jeon, S. Kim, J.S. Kim, "Bio-oil from rice straw by pyrolysis using fluidized bed and char removal system," Prepr. Pap.-Am. Chem. Soc., Fuel Che., vol. 49, pp. 801, 2004.
[27] F. Shafizadeh, "Introduction to pyrolysis of biomass," Journal of Analytical and Applied Pyrolysis., vol. 3, pp. 283-305, 1982.
[28] R. Zanzi, "Pyrolysis of biomass," Royal Institute of Technology, KTH, Stockholm, Sweden. PhD Thesis, 2001.
[29] D. Radlein, "In fast pyrolysis of biomass: A Handbook, Vol.2; Bridgwater AV, editor. Newbury, UK: CPL Press; 2002, p.165.
[30] T.R. Nuun, J.B. Howard, J.P.I. Longwell, W.A. Peters, "Product compositions and kinetics in the rapid pyrolysis of sweet gum hardwood," Ind.Eng.Chem. Process res. Dev., vol. 24, pp. 836-844 1985.
[31] D.S. Scott, J. Piskorz, M.A. Bergougnou, R. Graham, R.P. Overend, "The role of temperature in the fast pyrolysis of cellulose and wood," Ind.Eng.Chem.Res., vol. 27, pp. 8-15, 1988.
[32] A. Oasmaa, K. Sipila, Y. Solantausta, E. Kuoppala, "Quality improvement of pyrolysis liquid: effect of light volatiles on the stability of pyrolysis liquids," Energy and Fuels, vol. 6, pp. 2556-2561, 2005.
[33] J.P. Diebold, "The cracking kinetics of depolymerised biomass vapors in a continuous, tubular reactor," Colorado School of Mines: Golden, CO. Master Thesis, 1985.
[34] J.W. Rose, J.R. Cooper. Technical data on fuel. In: 7th edn, British National Comitte, World energy conference, London.