Preparation and Characterisation of Chemically Activated Almond Shells by Optimization of Adsorption Parameters for Removal of Chromium VI from Aqueous Solutions
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Preparation and Characterisation of Chemically Activated Almond Shells by Optimization of Adsorption Parameters for Removal of Chromium VI from Aqueous Solutions

Authors: Inamullah Bhatti, Khadija Qureshi, R. A. Kazi, Abdul Khalique Ansari

Abstract:

Activated carbon was prepared from agricultural waste “almond (Prunus amygdalus) nut shells" by chemical activation with phosphoric acid as an activating agent at 450 °C for 24 hr soaking time. The physical and chemical properties were analyzed. The adsorption of chromium VI from aqueous solution on almond nut shell activated carbon (ASAC) was investigated. The adsorption process parameters pH, agitation speed, agitation time, adsorbent dose were optimized. 98% of Cr VI was sorbed at pH 2 and stirring speed 200 rpm.. Surface structure showed that ASAC has a spongy type structure showing large number of pores

Keywords: adsorption, sorbent , sorbate and activation

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1080233

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References:


[1] Cieslak- Golonka Maria, "Toxic and mutagenic effects of chromium VI", Polyhedran, aug 1996, vol 15, No 21, pp 3667-3918.
[2] Raji C and Anirudhan TS (1998) Water Res. 32.3772.
[3] Patterson J.W (1985) industrial wastewater treatment technology, 2nd edn, Butterworth- Heinemann London.
[4] EPA (1990) Environmrental Pollution Control Alternatives EPA/625/5-90/25, EPA/625/4-89/023, Environmental Protection Agency Cincinaati OH USA.
[5] Juang R.S and Shiau R.C, " Metal removal from aqueous solution using chitosan enhanced membrane filtration", Journal of membrane science , feb 2000, vol 165, no2, pp159-167.
[6] Yan G and Viraraghavan T" Heavy metal removal in a biosorption column by immobilized M rouxii biomass", Bioresource technology, july 2001, vol 78, no3, pp 243-249.
[7] Tan, WT, Ooi S.T and Lee CK (1993) Environ technol 14.277.
[8] Alaerts G.J, Jitjaturant V and Kelderman P (1989), Water Sci Technol 21,1701
[9] Selomulya C, Meeyoo V and Amal R (1999) J Chem Technol Biotechnol , 74, 111.
[10] Hmadi NK , Chen XD, Farid MM and LU, MGQ (2001), chem. Eng J (Lausanne), 84,95.
[11] Dakiky M Khamis, M M anassra A and Merb M (2002), Adv Environ Res 6, 533.
[12] Srivastava S.K Tyagi R and Pant N (1989), "Water Res 23 1161.
[13] Ranganathan K (2000) Bioresource Technol 73,99.
[14] Rao M P arwate A.V AND Bhole AG (2002) Wate Manage 22,821.
[15] M K obya " Adsorption kinetic equilibrium and studies of Cr (VI) by hazelnut shell activation carbon " Adsorption Science and Technology, Vol 22, no 1 2004
[16] N Ahalya , RD Kanamadi, tv Ramachandra, " Biosorption of chromium (VI) from aqueous solution by the husk of Bengal gram, Electronic Journal of Biotechnology, v8, no 3 dec 2005.
[17] W.T Tsai, CY Chang , MC Lin , SF Chien, H.F Sun , MF Hsieh , Characterization of activated carbons prepared from sugarcane bagasse activation " journal of Environmental science and health, vol 36, no3 2001, pp365-378.
[18] S F Montanher , EA Oliveira, MC Rollemberg, "Removalo of metal ion from aqueous solutions by sorption onto rice bran", Journal of hazardous material, 117 (2005) 207-211.
[19] Yupeng Guo, Jurui Qi, Shaofeng Yang, Kaifeng Yu, Zichen Wang and Hongding XU, "Adsorption of Cr (VI) on micro and mesoporous rice husk based activated carbon" Material chemistry and Physics vol 78 issue 1 feb 2003 pp132-137.
[20] Fedral Bureau of Statistics Dvision of Pakistan june 2006.
[21] CA Toles, WE Marshall and M.M john "Granular activated carbons from nutshells for the uptake of metals and organic compounds", Pergamon, 6223(97) 73.
[22] D Perrin , B Dempsey, ÔÇÿBuffers for pH and metal ion control ," John Wiley and sons Inc New York 1974.
[23] EA Oliveria, SF Montanher , AD Andrader, JA Nobrega, MC Rollemberg, (2005) "Equilibrium studies for the sorption of chromium and nickel from aqueous solution using rice bran", Process Chemistry ,Vol 40, Dec 2005, pp. 3485-3490
[24] Ahmedna M, John MM, Clarke SJ, Marshall WE, Rao RM 1997 b, "Potential of agricultural by products based activated carbon for use in raw sugar decolorization", J food A gri, 75 117-124.
[25] American Water Works Association, AWWA Standards for granular activated carbons American Water Works Association , ANSI/AWWA B604-90 Denver Co 1991.
[26] Alaerts GJ, Jitjaturunt V, Kelderman P, (1989), " use of coconut shell based activated carbon for chromium VI removal" Water Science Technol , Vol 21, Jan 1989, pp.701-1704
[27] N Ahalya , RD Kanamadi, TV Ramachandra (2005) "Biosorption of chromium from aqueous solution by the husk of bengal gram (cicer arientInum), Environmental Biotechnology, Vol 8, No.3, Dec 2005, pp134-143 G. O. Young, "Synthetic structure of industrial plastics (Book style with paper title and editor)," in Plastics, 2nd ed. vol. 3, J. Peters, Ed. New York: McGraw-Hill, 1964, pp. 15-64.