@article{(Open Science Index):https://publications.waset.org/pdf/12520,
	  title     = {[Ti(OC4H9)4/2,5-Dimethoxytetrahydrofuran/ TEA/Ethylene Chlorobromide] as a Novel Homogeneous Catalyst System Effective for the Ethylene Dimerization Reaction},
	  author    = {Seyed Hamed Mahdaviani and  Davood Soudbar and  Matin Parvari},
	  country	= {},
	  institution	= {},
	  abstract     = {In the present research, the titanium-catalyzed
ethylene dimerization and more specifically, the concomitant byproducts
and polymer formation have been studied in the presence of 2,5-dimethoxytetrahydrofuran as an electron donor compound in the
combination with triethylaluminium (TEA) as activator. Then, we
added ethylene chlorobromide as a new efficient promoter to the
relevant catalyst system. Finally, the behavior of novel homogeneous
[Titanium tetrabutoxide (Ti(OC4H9)4)/2,5-dimethoxytetrahydrofuran/
TEA/ethylene chlorobromide] was investigated in the various
operating conditions for the optimum production of 1-butene. In the
optimum conditions, a very high ethylene conversion (almost 90.77
%), a relative high selectivity to 1-butene (79.00 %), yield of reaction equal to 71.70 % and a significant productivity (turnover frequency
equal to 1370 h-1) were achieved.},
	    journal   = {International Journal of Chemical and Molecular Engineering},
	  volume    = {5},
	  number    = {5},
	  year      = {2011},
	  pages     = {447 - 452},
	  ee        = {https://publications.waset.org/pdf/12520},
	  url   	= {https://publications.waset.org/vol/53},
	  bibsource = {https://publications.waset.org/},
	  issn  	= {eISSN: 1307-6892},
	  publisher = {World Academy of Science, Engineering and Technology},
	  index 	= {Open Science Index 53, 2011},
	}