%0 Journal Article
	%A Liang Zhang and  Hai-Tao Zhang and  W ei-Yong Ying and  Ding-Ye Fang 
	%D 2011
	%J International Journal of Chemical and Molecular Engineering
	%B World Academy of Science, Engineering and Technology
	%I Open Science Index 59, 2011
	%T Intrinsic Kinetics of Methanol Dehydration over Al2O3 Catalyst
	%U https://publications.waset.org/pdf/10636
	%V 59
	%X Dehydration of methanol to dimethyl ether (DME)
over a commercial Al2O3 catalyst was studied in an isothermal integral
fixed bed reactor. The experiments were performed on the temperature
interval 513-613 K, liquid hourly space velocity (LHSV) of 0.9-2.1h-1,
pressures between 0.1 and 1.0 MPa. The effect of different operation
conditions on the dehydration of methanol was investigated in a
laboratory scale experiment. A new intrinsic kinetics equation based
on the mechanism of Langmuir-Hinshelwood dissociation adsorption
was developed for the dehydration reaction by fitting the expressions
to the experimental data. An activation energy of 67.21 kJ/mol was
obtained for the catalyst with the best performance. Statistic test
showed that this new intrinsic kinetics equation was acceptable.
	%P 943 - 948