@article{(Open Science Index):https://publications.waset.org/pdf/10005810,
	  title     = {Synthesis of Vic-Dioxime Palladium (II) Complex: Precursor for Deposition on SBA-15 in ScCO2},
	  author    = {Asım Egitmen and  Aysen Demir and  Burcu Darendeli and  Fatma Ulusal and  Bilgehan Güzel},
	  country	= {},
	  institution	= {},
	  abstract     = {Synthesizing supercritical carbon dioxide (scCO2) soluble precursors would be helpful for many processes of material syntheses based on scCO2. Ligand (amphi-(1Z, 2Z)-N-(2-fluoro-3-(trifluoromethyl) phenyl)-N'-hydroxy-2-(hydroxyimino) were synthesized from chloro glyoxime and flourus aniline and Pd(II) complex (precursor) prepared. For scCO2 deposition method, organometallic precursor was dissolved in scCO2 and impregnated onto the SBA-15 at 90 °C and 3000 psi. Then the organometallic precursor was reduced with H2 in the CO2 mixture (150 psi H2 + 2850 psi CO2). Pd deposited support material was characterized by ICP-OES, XRD, FE-SEM, TEM and EDX analyses. The Pd loading of the prepared catalyst, measured by ICP-OES showed a value of about 1.64% mol/g Pd of catalyst. Average particle size was found 5.3 nm. The catalytic activity of prepared catalyst was investigated over Suzuki-Miyaura C-C coupling reaction in different solvent with K2CO3 at 50 oC. The conversion ratio was determined by gas chromatography.
},
	    journal   = {International Journal of Chemical and Molecular Engineering},
	  volume    = {10},
	  number    = {11},
	  year      = {2016},
	  pages     = {1388 - 1392},
	  ee        = {https://publications.waset.org/pdf/10005810},
	  url   	= {https://publications.waset.org/vol/119},
	  bibsource = {https://publications.waset.org/},
	  issn  	= {eISSN: 1307-6892},
	  publisher = {World Academy of Science, Engineering and Technology},
	  index 	= {Open Science Index 119, 2016},
	}