Jaroslav Císař

Publications

1 Comparison of Processing Conditions for Plasticized PVC and PVB

Authors: Michael Tupý, Dagmar Měřínská, Alice Tesaříková-Svobodová, Jaroslav Císař, Pavel Mokrejš

Abstract:

It is the worldwide problem that the recycled PVB is not recycled and it is wildly stored in landfills. However, PVB has similar chemical properties such as PVC. Moreover, both of these polymers are plasticized. Therefore, the study of thermal properties of plasticized PVC and the recycled PVB obtained by recycling of windshields is carried out. This work has done in order to find nondegradable processing conditions applicable for both polymers. Tested PVC contained 38% of plasticizer diisononyl phthalate (DINP) and PVB was plasticized with 28% of triethylene glycol, bis(2-ethylhexanoate) (3GO). The thermal and thermo-oxidative decomposition of both vinyl polymers are compared by calorimetric analysis and by tensile strength analysis.

Keywords: Recycling, Thermal analysis, Reprocessing, Decomposition, poly(vinyl butyral), poly(vinyl chloride)

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Abstracts

1 Comparison of Processing Conditions for Plasticized PVC and PVB

Authors: Michael Tupý, Dagmar Měřínská, Alice Tesaříková-Svobodová, Jaroslav Císař, Pavel Mokrejš

Abstract:

The worldwide problem is that the recycled PVB is wildly stored in landfills. However, PVB have very similar chemical properties such as PVC. Moreover, both of them are used in plasticized form. Thus, the thermal properties of plasticized PVC obtained from primary production and the PVB was obtained by recycling of windshields are compared. It is carried out in order to find degradable conditions and decide if blend of PVB/PVC can be processable together. Tested PVC contained 38 % of plasticizer diisononyl phthalate (DINP) and PVB was plasticized with 28 % of triethylene glycol, bis(2-ethylhexanoate) (3GO). Thermal and thermo-oxidative decomposition of both vinyl polymers are compared such as DSC and OOT analysis. The tensile strength analysis is added.

Keywords: Recycling, Thermal analysis, Reprocessing, Decomposition, polyvinyl chloride, polyvinyl butyral

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