Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 4

cobalt Related Publications

4 Laboratory Evaluation of the Flotation Response of a Copper Cobalt Oxide Ore to Gasoil-Rinkalore Mixtures

Authors: M. B. Kime, J. Ntambwe, J. Mwamba

Abstract:

Froth flotation remains to date as one of the most used metallurgical processes for concentrating metal-bearing minerals in ores. Oxide ores are relatively less amenable to froth flotation and require a judicious choice of reagents for the recovery of metals to be optimised. Laboratory batch flotation tests were conducted to determine the effect of two types of gasoil-rinkalore mixtures on the flotation response of a copper cobalt oxide ore sample. The head assay conducted on the initial ore sample showed that it contained about 2.90% of Cu, 0.12% of Co. Upon the flotation test work, the results obtained indicated that the concentrate obtained with use of the mixture gazoil-rinkalore RX yielded 8.24% Cu and 0.22% Co concentrate grades with recoveries of 76.0% Cu and 78.0% Co respectively. But, the concentrate obtained by use of the mixture gazoil-rinkalore RX3 yielded relatively bad results with 5.92% Cu and 0.18% Cu concentrate grades with recoveries of 70.3% Cu and 65.3% Co respectively.

Keywords: Copper, froth flotation, cobalt, Rinkalore RX, Rinkalore RX3, Shangolowe

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2473
3 Progressive Loading Effect of Co over SiO2/Al2O3 Catalyst for Cox Free Hydrogen and Carbon Nanotubes Production via Catalytic Decomposition of Methane

Authors: Sushil Kumar Saraswat, K. K. Pant

Abstract:

Co metal supported on SiO2 and Al2O3 catalysts with a metal loading varied from 30 of 70 wt.% were evaluated for decomposition of methane to COx free hydrogen and carbon nanomaterials. The catalytic runs were carried out from 550-800oC under atmospheric pressure using fixed bed vertical flow reactor. The fresh and spent catalysts were characterized by BET surface area analyzer, XRD, SEM, TEM and TG analysis. The data showed that 50% Co/Al2O3 catalyst exhibited remarkable higher activity at 800oC with respect to H2 production compared to rest of the catalysts. However, the catalytic activity and durability was greatly declined at higher temperature. The main reason for the catalytic inhibition of Co containing SiO2 catalysts is the higher reduction temperature of Co2SiO4. TEM images illustrate that the carbon materials with various morphologies, carbon nanofibers (CNFs), helical-shaped CNFs and branched CNFs depending on the catalyst composition and reaction temperature were obtained.

Keywords: Carbon Nanotubes, Hydrogen production, cobalt, methane decomposition

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2273
2 Separation of Manganese and Cadmium from Cobalt Electrolyte Solution by Solvent Extraction

Authors: Shafiq Alam, Mirza Hossain, Hesam Hassan Nejad

Abstract:

Impurity metals such as manganese and cadmium from high-tenor cobalt electrolyte solution were selectively removed by solvent extraction method using Co-D2EHPA after converting the functional group of D2EHPA with Co2+ ions. The process parameters such as pH, organic concentration, O/A ratio, kinetics etc. were investigated and the experiments were conducted by batch tests in the laboratory bench scale. Results showed that a significant amount of manganese and cadmium can be extracted using Co-D2EHPA for the optimum processing of cobalt electrolyte solution at equilibrium pH about 3.5. The McCabe-Thiele diagram, constructed from the extraction studies showed that 100% impurities can be extracted through four stages for manganese and three stages for cadmium using O/A ratio of 0.65 and 1.0, respectively. From the stripping study, it was found that 100% manganese and cadmium can be stripped from the loaded organic using 0.4 M H2SO4 in a single contact. The loading capacity of Co-D2EHPA by manganese and cadmium were also investigated with different O/A ratio as well as with number of stages of contact of aqueous and organic phases. Valuable information was obtained for the designing of an impurities removal process for the production of pure cobalt with less trouble in the electrowinning circuit.

Keywords: cadmium, manganese, cobalt, solvent extraction, D2EHPA

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 3451
1 Mathematical Simulation of Acid Concentration Effects during Acid Nitric Leaching of Cobalt from a Mixed Cobalt-Copper Oxide

Authors: Ek Ngoy, A F Mulaba-Bafubiandi

Abstract:

Cobalt was acid nitric leached from a mixed cobaltcopper oxide with variable acid concentration. Resulting experimental data were used to analyze effects of increase in acid concentration, based on a shrinking core model of the process. The mathematical simulation demonstrated that the time rate of the dissolution mechanism is an increasing function of acid concentration. It was also shown that the magnitude of the acid concentration effect is time dependent and the increase in acid concentration is more effective at earlier stage of the dissolution than at later stage. The remaining process parameters are comprehensively affected by acid concentration and their interaction is synergetic.

Keywords: Simulation, Leaching, cobalt, Acid effect, Cobalt-copper oxide

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1526