Effect of Concentration of Sodium Borohydrate on the Synthesis of Silicon Nanoparticles via Microemulsion Route
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32797
Effect of Concentration of Sodium Borohydrate on the Synthesis of Silicon Nanoparticles via Microemulsion Route

Authors: W. L. Liong, Srimala Sreekantan, Sabar D. Hutagalung

Abstract:

The effect of concentration of reduction agent of sodium borohydrate (NaBH4) on the properties of silicon nanoparticles synthesized via microemulsion route is reported. In this work, the concentration of the silicon tetrachloride (SiCl4) that served as silicon source with sodium hydroxide (NaOH) and polyethylene glycol (PEG) as stabilizer and surfactant, respectively, are keep fixed. Four samples with varied concentration of NaBH4 from 0.05 M to 0.20 M were synthesized. It was found that the lowest concentration of NaBH4 gave better formation of silicon nanoparticles.

Keywords: Microelmusion, nanoparticles, reduction, silicon

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1073673

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1922

References:


[1] Q. Liu, S. M. Kauzlarich, "A new synthetic route for the synthesis of hydrogen terminated silicon nanoparticles," Materials Science and Engineering B96 (2002) 72-75.
[2] M. R. Scriba, C. Arendse, M. Harting and D. T. Britton, "Hot wire synthesis of Si nanoparticles," Journal of Thin Solid Films 516(2008)844-846.
[3] F. Fabbri, E. Borsella, M. Carpanesel, R. Fantoni, R. Caterino, R. D-Amato, M. Falconieri and E. Serra, "Size and surface control of optical properties in silicon nanoparticles," Advances in Science and Technology Vol. 45 (2006) pp. 2620-2626.
[4] M. Leparoux, M. Loher, C. Schreuders and S. Siegmann, "Neural network modelling of the inductively coupled RF plasma synthesis of silicon nanoparticles," Journal of Powder Technology 185 (2008) 109 - 115.
[5] P.V. Adhyapak, P. Karandikar, K. Vijayamohananb, A. A. Athawale, A.J. Chandwadkar, "Synthesis of silver nanowires inside mesoporous MCM-41 host," Materials Letters 58 (2004) 1168- 1171.
[6] P. Kim, J.B. Joo, W. Kim, J. Kim, I.K. Song, J. Yi, "NaBH4-assisted ethylene glycol reduction for preparation of carbon-supported Pt catalyst for methanol electro-oxidation," Journal of Powder Sources 160 (2006) 987-990.
[7] Y. Torisawa, T. Nishi, J. Minamikawa, "Some aspects of NaBH4 reduction in NMP," Bioorganic & Medicinal Chemistry 10 (2002) 2583-2587.
[8] D.H. Chen, and S.H. Wu, "Synthesis of nickel nanoparticles in waterin- oil microemulsions," Chem. Mater. 2000, 12, 1354-1360.
[9] A. Pal, S. Shah, S. Belochapkine, D. Tanner, E. Magner, S. Devi, "Room temperature synthesis of platinum nanoparticles in water-in-oil micoremulsion," Colloids and surfaces A: Physicochem. Eng. Aspects 337(2009)205-207.
[10] R. Hua, C. Zang, C. Shao, D. Xie and C. Shi, "Synthesis of barium fluoride nanoparticles from microemulsion," Nanotechnology 14(2003)588-591.
[11] S.D. Hutagalung, A. Ahmad, K.A. Yaacob, "Growth of silicon nanostrucctures by thermal evaporation uusing nickel catalyst," Solid State Science and Technology, Vol. 16 No. 1 (2008) 100 -106.
[12] Y. Shin, D. Lee, K. Lee, K.H. Ahn, B. Kim, Surface Properties of the Silica Nanoparticles Modified with Polymer Nanocomposite Applications, Journal of Industrial and Engineering Chemistry 14 (2008) 515-519.
[13] G. Molinuex, Pegylation: Engineering Improved Pharmaceuticals for Enhanced Therapy, Cancer Treatment Review 2002: 28 (SUPPL. A): 13-16.
[14] Z. Zhang, A.E. Berns, S. Willbold, J. Buitenhuis, Synthesis of Poly(ethylene glycol) (PEG)-Grafted Colloidal Silica Particles with Improved Stability In Aqueous Solvent, Journal of Colloid and Interface Science 310 (2007) 446-455.
[15] K. B. Musabekov., S. B.Aidarova, S. M. Andreyeva, M. B. Isabaeva, "Influence of surfactants and their combination with polyethylene glycol on the stability of sunflower oil-water emulsions," CAB 2009.
[16] J. Klangsin, O. Marty, J. Munguia, V. Lysenko, A. Vorobey, M. Pitaval, A. Cereyon, A. Pillonnet, B. Champagnon, "Structural and luminescent properties of silicon nanoparticles incorporated into zirconia matrix," Physic Letters A372 (2008) 1508-1511.
[17] C. Meier, S. Luttjohann, V.G. Kravets, H. Nienhaus, A. Lorke, H. Wiggers, "Raman properties of silicon nanoparticles," Physica E 32 (2006) 155-158.
[18] S. Kalele, S. W. Gosavi, J. Urban, S. K. Kulkarni., "Nanoshell particles: synthesis, properties and applications, Current Science," Volume 91, No. 8, pp 1038-1052.
[19] K.R. Catchpole, S. Pillai, "Surface plasmons for enhanced silicon light-emittingndiodes and solar cells," Journal of Luminescence 121 (2006) 315-318.