WASET
	%0 Journal Article
	%A Chihhao Fan and  Ming-Chu Liao
	%D 2009
	%J International Journal of Chemical and Molecular Engineering
	%B World Academy of Science, Engineering and Technology
	%I Open Science Index 35, 2009
	%T The Mechanistic and Oxidative Study of Methomyl and Parathion Degradation by Fenton Process
	%U https://publications.waset.org/pdf/8825
	%V 35
	%X The purpose of this study is to investigate the chemical
degradation of the organophosphorus pesticide of parathion and
carbamate insecticide of methomyl in the aqueous phase through
Fenton process. With the employment of batch Fenton process, the
degradation of the two selected pesticides at different pH, initial
concentration, humic acid concentration, and Fenton reagent dosages
was explored. The Fenton process was found effective to degrade
parathion and methomyl. The optimal dosage of Fenton reagents (i.e.,
molar concentration ratio of H2O2 to Fe2+) at pH 7 for parathion
degradation was equal to 3, which resulted in 50% removal of
parathion. Similarly, the optimal dosage for methomyl degradation
was 1, resulting in 80% removal of methomyl. This study also found
that the presence of humic substances has enhanced pesticide
degradation by Fenton process significantly. The mass spectroscopy
results showed that the hydroxyl free radical may attack the single
bonds with least energy of investigated pesticides to form smaller
molecules which is more easily to degrade either through
physio-chemical or bilolgical processes.
	%P 616 - 620