Characterization of Chemically Modified Biomass as a Coating Material for Controlled Released Urea by Contact Angle Measurement
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32797
Characterization of Chemically Modified Biomass as a Coating Material for Controlled Released Urea by Contact Angle Measurement

Authors: Nur Zahirah Zulhaimi, KuZilati KuShaari, Zakaria Man

Abstract:

Controlled release urea has become popular in agricultural industry as it helps to solve environmental issues and increase crop yield. Recently biomass was identified to replace the polymer used as a coating material in the conventional coated urea. In this paper spreading and contact angle of biomass droplet (lignin, cellulose and clay) on urea surface are investigated experimentally. There were two tests were conducted, sessile drop for contact angle measurement and pendant drop for contact angle measurement. A different concentration of biomass droplet was released from 30 mm above a substrate. Glass was used as a controlled substrate. Images were recorded as soon as the droplet impacted onto the urea before completely adsorb into the urea. Digitized droplets were then used to identify the droplet-s surface tension and contact angle. There is large difference observed between the low surface tension and high surface tension liquids, where the wetting and spreading diameter is higher for lower surface tension. From the contact angle results, the data showed that the biomass coating films were possible as wetting liquid (θ < 90º). Contact angle of biomass coating material gives good indication for the wettablity of a liquid on urea surface.

Keywords: Fluid, Dynamics, Droplet, Spreading, Contact Angle, Surface Tension.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1057641

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2429

References:


[1] Iovino R., Zullo R., Rao M.A., Cassar L., Gianfreda L. Biodegradation of poly(lactic acid)/starch/coir biocomposites under controlled composting conditions (2008) PolymerDegradation and Stability, 93 (1), pp. 147-157.
[2] Puechner P., Mueller W.-R., Bardtke D. Assessing the biodegradation potential of polymers in screening- and long-term test systems (1995) Journal of Environmental Polymer Degradation, 3 (3), pp. 133¬143.
[3] J. K. Kiran, Y. M. Khanif, H. Amminuddin, A. R. Anuar, " Effect of Controlled Release Urea on theYield and Nitrogen Nutrition of Flooded Rice", Comm. Soil Science and Plant Anal, 2010, 41, 811-819
[4] M. Tomaszewska and A. Jarosiewicz, "Polysulfone Coating with Starch Addition in CRF Formulation," Desalination, 2004, 163, 247-252.
[10]dr zak
[5] Guo, M., Liu, M., Zhan, F., Wu, L. (2005). Preparation and properties of a slow-release membrane-encapsulated urea fertilizer with superabsorbent and moisture preservation. Industrial Engineering Chemistry Research, 44, 42064211.
[6] Yongsong Cao, Lu Hang, Jiuxin Chen, Ji Liang, Shengyou Long, Yitong Lu, (2005) Development of a controlled release formulation based on a starch matrix system. International Journal of Pharmaceutics 298 108- 116
[7] Boli Ni, Mingzhu Liu, Shaoyu Lu, (2009) Multifunctional Slow-Release Urea Fertilizer from ethylcellulose and superabsorbent coated formulation, Chemical Engineering Journal 155 892-898
[8] Jonathan E Stringer, Patrick J Smith and Brian Derby. (2005) Droplet Behaviour in Inkjet Printing, School of Materials, University of Manchester.
[9] Derrick O.N, Esio. O.Rhoda.H. (2001) Determination of contact angle from contact area of liquid droplet spreading on solid substrate.
[10] Oukach et. al., 2010, "Deformation Behavior of a Liquid Droplet Impacting a Solid Surface," COMSOL Conference Proceedings, Paris, 2010.
[11] Chi-Chuan HWANG, Yeau-Ren JENG, Yu-Lin HSU and Jee-Gong CHANG. (2001) Molecular Dynamics Simulation of Microscopic Droplet Spread on Rough Surfaces. Physical Society of Japan Vol. 70, No. 9, pp. 2626-2632.
[12] F.Depypere, P. Van Oostveldt, J.G Pieters, K. Dewettinck, (2009) Quantification of microparticle coating quality by confocal laser scanning microscopy (CLSM). European journal of pharmaceutics and Biopharmaceutics 73 (2009) 179-186.
[13] Li Chen, Zhigang Xie, Xiuli Zhuang, Xuesi Chen, Xiabin Jing, (2008) Controlled release of Urea encapsulated by starch-g-poly ( L-lactide) 342-348
[14] KuShaari, K. (2007), Coating uniformity on a pharmaceutical tablet: An experimental study and fmite volume modeling of droplet impact behavior, PhD Dissertation.
[15] Moita, A. S. H., and Moreira, A. L. N., (2003), Influence of surface properties on the dynamic behavior of impacting droplets, 9th International Conference on Liquid Atomization and Spray Systems.