Development of Quasi-Two-Dimensional Nb2O5 for Functional Electrodes of Advanced Electrochemical Systems
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32804
Development of Quasi-Two-Dimensional Nb2O5 for Functional Electrodes of Advanced Electrochemical Systems

Authors: S. Zhuiykov, E. Kats

Abstract:

In recent times there has been a growing interest in the development of quasi-two-dimensional niobium pentoxide (Nb2O5) as a semiconductor for the potential electronic applications such as capacitors, filtration, dye-sensitised solar cells and gas sensing platforms. Therefore once the purpose is established, Nb2O5 can be prepared in a number of nano- and sub-micron-structural morphologies that include rods, wires, belts and tubes. In this study films of Nb2O5 were prepared on gold plated silicon substrate using spin-coating technique and subsequently by mechanical exfoliation. The reason this method was employed was to achieve layers of less than 15nm in thickness. The sintering temperature of the specimen was 800oC. The morphology and structural characteristics of the films were analyzed by Atomic Force Microscopy (AFM), Raman Spectroscopy, X-ray Photoelectron Spectroscopy (XPS).

Keywords: Mechanical exfoliation, niobium pentoxide, quazitwo- dimensional, semiconductor, sol-gel, spin-coating, two dimensional semiconductors.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1055789

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2352

References:


[1] A.M. Taurino, A. Forleo, L. Francioso, P. Siciliano, M. Stalder and P. Nesper, "Synthesis, electrical characterization and gas sensing properties of molybdenum oxide nanorods", Appl. Phys. Lett., vol. 88, pp.15211, 2006.
[2] J.Z. Ou, R.A. Rani, M.H. Ham, M. R. Field, Y. Zhang, H. Zheng, P. Reece, S. Zhuiykov, S. Sriram, M. Bhaskaran, R.B. Kaner and K. Kalantar-zadeh, "Elevated temperature anodized Nb2O5 - a photoanode material with exceptionally large photoconversion", ASC Nano, vol. 6, pp. 4045-4053, 2012.
[3] S. Balendhran, J. Deng, J. Ou, S. Walia, J. Scott, J. Tang, K. Wang, M. Field, S. Russo, S. Zhuiykov, M. Strano, N. Medhekar, S. Sriram, M. Bhaskaran and K. Kalantar Zadeh, "Large carrier mobility in high-k two-dimensional metal oxides", Advanced Materials, vol. 25, pp.109- 114, 2013.
[4] S. Zhuiykov and E. Kats, "Atomically-thin two-dimensional materials for functional electrodes of electrochemical devices: A review," Ionics, vol. 19, pp.825-865, 2013.
[5] Q. Zhang and G.Cao, "Nanostructured photoelectrodes for dyesensitized solar cells," Nano Today, vol. 6, pp. 91-109, 2011.
[6] M. D. Wei, Z. M Qi, M. Ichihara and H. S. Zhou, "Synthesis of singlecrystal niobium pentoxide nanobelts," Acta Mater., vol. 56, pp. 2488- 2494, 2008.
[7] J. Xia, N. Massaki, K. Jiang and S. Yanagida, "Fabrication and characterization of thin Nb2O5 blocking layers for ionic liquid-based dye-sensitized solar cells," J. Photochem Photobio A: Chem., vol. 188, pp. 120-127, 2007.