Extractable Heavy Metal Concentrations in Bottom Ash from Incineration of Wood-Based Residues in a BFB Boiler Using Artificial Sweat and Gastric Fluids
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32804
Extractable Heavy Metal Concentrations in Bottom Ash from Incineration of Wood-Based Residues in a BFB Boiler Using Artificial Sweat and Gastric Fluids

Authors: Risto Pöykiö, Olli Dahl, Hannu Nurmesniemi

Abstract:

The highest extractable concentration in the artificial sweat fluid was observed for Ba (120mg/kg; d.w.). The highest extractable concentration in the artificial gastric fluid was observed for Al (9030mg/kg; d.w.). Furthermore, the extractable concentrations of Ba (550mg/kg; d.w.) and Zn (400mg/kg: d.w.) in the bottom ash using artificial gastric fluid were elevated. The extractable concentrations of all heavy metals in the artificial gastric fluid were higher than those in the artificial sweat fluid. These results are reasonable in the light of the fact that the pH of the artificial gastric fluid was extremely acidic both before (pH 1.54) and after (pH 1.94) extraction, whereas the pH of the artificial sweat fluid was slightly alkaline before (pH 6.50) and after extraction (pH 8.51).

Keywords: Ash, artificial fluid, heavy metals, in vitro, waste.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1088078

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2889

References:

  1. M. Intawongse, J.R. Dean, “In-vitro testing for assessing oral bioaccessibility of trace metals in soil and food samples”, Trends Anal. Chem., vol. 25, nro. 9, pp. 876-886, 2006.
  2. I. Rezić, I. Staffan, “ICP-OES determination of metals present in textile materials”, Microchem. J., vol. 85, nro. 1, pp. 46-51, 2007.
  3. J. Zhang, I. K. Han, L. Zhang, W. Crain, “Hazardous chemicals in synthetic turf materials and their bioaccessibility in digestive fluids”, J. Exp. Sci. Env. Epid., vol. 18, nro. 6, pp. 600-607, 2008.
  4. I. Rezić, M. Zeiner, I. Steffan, “Determination of allergy-causing metals from coins”, Monatsh. Chem., vol. 140, nro. 2, 147-151, 2009.
  5. J. Streit, L.C. Tran-Ho, E. Königsberger, “Solubility of the three calcium oxalate hydrates in sodium chloride solutions and urine-like liquors”, Monatsh. Chem., vol. 129, nro. 12, pp. 1225-1236, 1998.
  6. S.G. Lu, Y.Y. Chen, H.D. Shan, S.Q. Bai, “Mineralogy and heavy metal leachability of magnetic fractions separated from some Chinese coal fly ashes”, J. Hazard. Mater., vol. 169, nro. 1-3, pp. 246-255, 2009.
  7. M.C. Navarro, C. Pérez-Sirvent, M. J. Martinez-Sánchez, J. Vidal, J. Marimón, (2006). “Lead, cadmium and arsenic bioavailability in the abandoned mine site of Cabezo Rajao (Murcia, Se Spain)”, Chemosphere, vol. 63, nro. 3, pp. 484-489, 2006.
  8. R.P. Nūñez, R.D. Rey, A.B.M. Menduiña, M.T.B. Silva, “Physiologically based extraction of heavy metals in compost: Preliminary results”, J. Trace Elem. Med. Bio., vol. 21, nro. S1, pp. 83-85, 2007.
  9. S.B. Horowitz, B.L. Finley, “Using human sweat to extract chromium from chromite ore processing residue”, J. Toxicol. Env. Heal. A., vol. 40, nro. 4, pp. 585-599, 1993.
  10. J.H. Hong, K-O. Kim, “Operationally defined solubilization of copper and iron in human saliva and implications for metallic flavor perception”, Eur. Food Res. Technol., vol. 233, nro 6, pp. 973-983.
  11. V.W.H. Leung, B.W. Darvell, “Artificial salivas for in vitro studies of dental materials”, J. Dent., vol. 25, nro. 6, pp. 475-484, 1997.
  12. C.M.A. Brett, L. Muresan “The influence of artificial body fluids on metallic corrosion”, Key Eng. Mat., vol. 230-232, pp. 459-462, 2002.
  13. H. Nurmesniemi, K. Manskinen, R. Pöykiö, O. Dahl, “Forest fertilizer properties of the bottom ash and fly ash from a large-sized (115 MW) industrial power plant incinerating wood-based biomass residues”, J. Univ. Chem. Technol. Met. (Sofia), vol. 47, nro. 1, pp. 43-52, 2012.
  14. C. Yafa, J.G. Farmer, “A comparative study of acid-extractable and total digestion method for the determination of inorganic elements in peat material by inductively coupled plasma-optical emission spectrometry”, Anal. Chim. Acta., vol. 557, nro. 1-2, pp. 296-302, 2006.
  15. Y.W. Song, D.Y. Shan, E.H. Han, “Corrosion behaviours of electroless plating Ni-P coatings deposited on magnesium alloys in artificial sweat solution”, Electrochim. Acta, vol. 53, nro. 4, pp. 2009-2015, 2007.
  16. X.S. Wang, Y. Qin, Y.K. Chen, “Leaching characteristics of arsenic and heavy metals in urban roadside soils using a simple bioavailability extraction test”, Environ. Monit. Assess, vol. 129, nro. 1-3, pp. 221-226, 2007.
  17. J.Y. Kim, K.W. Kim, J.U. Lee, J.S. Lee, J. Cook, “Assessment of As and heavy metal contamination in the vicinity of Duckum Au-Ag Mine, Korea”, Environ. Geochem. Hlth., vol. 24, nro. 3, pp. 213-225, 2002.
  18. D.S. Kosson, H.A. Van Der Sloot, F. Sanchez, A.C. Garrabrants, “An integrated framework for evaluating leaching in waste management and utilization of secondary materials”, Environ. Eng. Sci., vol. 19, nro. 3, pp. 159-204, 2002.
  19. B.M. Steenari, O. Lindqvist, “Fly ash characteristics in co-combustion of wood with coal, oil or peat”, Fuel, vol. 78, nro. 4, pp. 479-488, 1999.
  20. G.S. Humphreys, D.M. Raven, R.J. Field, “Wood-ash stone in Angophora costata (Gaertn.) J. Britt. following Sydney busfires”, Aust. For., vol. 67, nro. 1, pp. 39-43, 2004.
  21. A. Meawad, D. Bojinova, Y. Pelovski, “Study on elements leaching from bottom ash of Enel Maritsa East3 thermal power plant in Bulgaria”, J. Univ. Chem. Technol. Met. (Sofia), vol. 45, nro. 3, pp. 275-282, 2010.
  22. S.L. Holmberg, T. Claesson, “Mineralogy of granulated wood ash from a heating plant in Kalmar, Sweden”, Environ. Geol., vol. 40, nro. 7, pp. 820-828, 2001.
  23. P. van Herck, C. Vandecasteele, “Evaluation of the use of a sequential extraction procedure for the characterization and treatment of metal containing solid waste”, Waste Manage., vol. 21, nro. 8, pp. 685-694, 2001.
  24. U.M. Mroueh, E. Mäkelä, M. Wahlström, J. Kauppila, J. Sorvari, P. Heikkinen, R. Salminen, M. Juvankoski, M. Tammirinne, ”By-products in earth construction. Assessment of acceptability”, National Technology Agency, Technology Reviewers 96/2000, pp. 39, 2000.
  25. U.M. Mroueh, M. Wahlström, “By-products and recycled materials in earth construction in Finland – an assessment of applicability”, Resour. Conserv. Recycl., vol. 35, nro. 1-2, pp. 117-129, 2002.
  26. J. Twining, P. McGlinn, E. Loi, K. Smith, R. Gieré, “Risk ranking of bioaccessible metals from fly ash dissolved in simulated lung and gut fluids”, vol. 39, nro. 19, pp. 7749-7756, 2005.
  27. U.M. Mroueh, E. Mäkelä, M. Wahlström, J. Kauppila, J. Sorvari, J. Puolanne, M. Kuvankoski, M. Tammirinne, P. Heikkinen, R. Salminen “Finnish guidance for the use of secondary products in earth and road construction.” In R. Salminen (Ed.), International conference on practical applications in environmental geotechnology ecogeo 2000. Geological Survey of Finland, Special Paper, 32(15-21), 2001.
  28. S.R. Al-Abed, P.L. Hageman, G. Jagedeesan, N. Madhavan, D. Allen, “Comparative evaluation of short-term leach tests for heavy metal release from mineral processing waste”, Sci. Total Environ., vol. 364, nro. 1-3 pp. 14-23, 2006.
  29. R. Pöykiö, H. Rönkkömäki, H. Nurmesniemi, P. Perämäki, K. Popov, I. Välimäki, ”Release of metals from grate-fired boiler cyclone ash at different pH values”, Chem. Spec. Bioavailab., vol. 21, nro. 1, pp. 23-31, 2009.