Investigation of Pre-Treatment Parameters of Rye and Triticale for Bioethanol Production
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32797
Investigation of Pre-Treatment Parameters of Rye and Triticale for Bioethanol Production

Authors: Algirdas Jasinskas, Egidijus Šarauskis, Raimondas Šarauskis, Antanas Sakalauskas

Abstract:

This paper presents the new results of energy plant – rye and triticale at yellow ripeness and ripe, pre-treatment in high pressure steam reactor and monosaccharide extraction. There were investigated the influence of steam pressure (20 to 22 bar), retention duration (180 to 240 s) and catalytic sulphuric acid concentration strength (0 to 0.5 %) on the pre-treatment process, contents of monosaccharides (glucose, arabinose, xylose, mannose) and undesirable by-compounds (furfural and HMF) in the reactor. The study has determined that the largest amount of monosaccharides (37.2 % of glucose, 2.7 % of arabinose, 8.4 % of xylose, and 1.3 % of mannose) was received in the rye at ripe, the samples of which were mixed with 0.5 % concentration of catalytic sulphuric acid, and hydrolysed in the reactor, where the pressure was 20 bar, whereas the reaction time – 240 s.

Keywords: Bioethanol, Pre-treatment, Rye, Triticale.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1078977

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1384

References:


[1] C. Berg, "World Ethanol Production", www.distill.com/world_ ethanol_production.html. 2012.
[2] M. Roehr, "The Biotechnology of Ethanol", Classical and Future Applications. Weinheim, 2001, 232 p.
[3] J. N. Saddler, L. P. Ramos and C. Breul, "Stream Pretreatment of Lignocellulosic Residues", Bioconversion of Forests and Agricultural Plant Residues. 1993, pp. 73-91.
[4] H. H. Dietrich, M. Sinner and J. Puls, "Potential of steaming hardwoods and straw for feed and food production", Holzforschung. 1998, vol. 32, pp. 193-199.
[5] R. H. Marchessault., S. Coulombe, T. Hanai and H. Morikawa, "Monomers and oligomers from wood", Pulp and Paper Magazine of Canada Trans. 1980, vol. 6, pp. 52-56.
[6] C. Tengborg, K. Stenberg, M. Galbe, G. Zacchi, S. Larsson, E. Palmqvist and B. Hahn-Hägerdal, "Comparison of SO2 and H2SO4 impregnation of softwood prior to steam pretreatment on ethanol production", Applied Biochemistry and Biotechnology. 1998, vol. 70- 72, pp. 3-15.
[7] Q. A. Nguyen, M. P. Tucker, F. A. Keller and F. P. Eddy, "Two-stage dilute acid pretreatment of softwoods", Applied Biochemistry and Biotechnology. 2000, vol. 84-86, pp. 561-576.
[8] B. Sanchez and J. Bautista, "Effects of Furfural and 5- hydroxymethylfurfural on the Fermentation of Saccharomyces cerevisiae and Biomass Production from Candida guilliermondii", Enzyme Microbial Technology. 1988, vol. 10, pp. 315-318.
[9] M. J. Taherzadeh, L. Gustafsson, C. Niklasson and G. Liden, "Physiological effects of 5-hydroxymethyl furfural (HMF) on Saccharomyces cerevisiae", Applied Microbiology and Biotechnology. 2000, vol. 53, no 6, pp. 701-708.
[10] C. Mart├¡n and L. J. Jönsson, "Comparison of the resistance of industrial and laboratory strains of Saccharomyces and Zygosaccharomyces to lignocellulose-derived fermentation inhibitors", Enzyme Microbial Technology. 2003, vol. 32, pp. 386-395.
[11] J. Puls, K. Poutanen, H. Korner and L. Viikari, "Biotechnical utilisation of wood carbohydrates after steaming pre-treatment", Applied Microbiology and Biotechnology. 1985, vol. 22, pp. 416-423.
[12] W. Schwald, T. Smaridge, M. Chan, C. Breuil and J. N. Saddler, "The influence of SO2 impregnation and Fractionation on product recovery and enzymic hydrolysis of steam-treated sprucewood", In Coughlan, M. P. Enzyme systems for lignocellulose degradation. Elsevier Applied Science, London and New York. 1989, pp. 231-242.
[13] L. Petrus and N. A. Noordermeer, "Biomass to biofuels, a chemical perspective", Green Chemistry. 2008, vol. 8, pp. 861-867.
[14] R. Marchal, M. Ropars and J. P. Vandecasteele, "Conversion into acetone and butanol of lignocellulosic substrates pretreated by steam explosion", Biotechnology Letters. 1986, vol. 8, pp. 365-370.
[15] I. E. Tenrud, O. Theander, L. Torneport and L. Vallander, "Changes in the chemical composition of steam-exploded wheat straw during enzymic hydrolysis", Enzyme and Microbial Technology. 1989, vol. 11, pp. 500-506.
[16] P. D├╝rre, "Biobutanol: an attractive biofuel", Biotechnology Journal. 2007, vol. 2, no 12, pp. 1525-1534