Graphene Oxide Fiber with Different Exfoliation Time and Activated Carbon Particle
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32804
Graphene Oxide Fiber with Different Exfoliation Time and Activated Carbon Particle

Authors: Nuray Uçar, Mervin Ölmez, Özge Alptoğa, Nilgün K. Yavuz, Ayşen Önen

Abstract:

In recent years, research on continuous graphene oxide fibers has been intensified. Therefore, many factors of production stages are being studied. In this study, the effect of exfoliation time and presence of activated carbon particle (ACP) on graphene oxide fiber’s properties has been analyzed. It has been seen that cross-sectional appearance of sample with ACP is harsh and porous because of ACP. The addition of ACP did not change the electrical conductivity. However, ACP results in an enormous decrease of mechanical properties. Longer exfoliation time results to higher crystallinity degree, C/O ratio and less d space between layers. The breaking strength and electrical conductivity of sample with less exfoliation time is some higher than sample with high exfoliation time.

Keywords: Activated carbon, coagulation by wet spinning, exfoliation, graphene oxide fiber.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1339786

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1593

References:


[1] Novoselov K. S., Geim A. K., Morozov S. V., Jiang D., Zhang Y., Dubonos S. V., Grigorieva I. V. and Firsov A. A., “Electric field effect in atomically thin carbon film,” Science, vol.306, 2004, 666.
[2] Cong, H.P., Ren, X.C., Wang, P., Yu, S.H., “Wet-spinning assembly of continuous, neat, and macroscopic graphene fibers,” Scientific Reports, vol.2, 2012, No.613, pp. 1-6.
[3] Jalili R., Aboutalebi, S. H., Esrafilzadeh, D., Shepherd, R. L., Chen, J., Aminorroaya-Yamini S., Konstantinov, K., Minett, A. I., Razal, J. M., Wallace, G. G., “Scalable one-step wet-spinning of graphene fibers and yarns from liquid crystalline dispersions of graphene oxide: Towards multifunctional textiles,” Advanced Functional Materials, vol.23, 2013, pp.5345-5354.
[4] Chen, L., He, Y., Chai, S., Qiang, H., Chen, F., Fu, Q., “Toward high performance graphene fibers,” Nanoscale, vol.5, 2013, pp.5809–5815.
[5] Shen H., Zhang L., Liu M., “Biomedical applications of graphene,” Theranostics, March, vol.2 (3), 2012, pp. 283-294.
[6] Huang X., Qui X., Boey F., Zhang H., “Graphene-based composites”, Chem. Soc. Rev, vol. 41, 2012, pp. 666–686.
[7] Li M., Zhang X., Wang X., Ru Y., Qiao J., “Ultrastrong graphene-based fibers with increased elongation”, Nano Letters, vol.16, 2016, pp. 6511−6515.
[8] Xu Z., Gao C., “Graphene fiber: a new trend in carbon fibers,” Materials Today, vol.18, 2015, pp. 480-492.
[9] Paulchamy B., Arthi G., Lignesh B.D., “A Simple approach to stepwise synthesis of graphene oxide nanomaterial”, J Nanomed Nanotechnol, vol. 6, 2015, No: 253. doi: 10.4172/2157-7439.1000253
[10] Fan, T., Zhao C., Xiao Z., Guo F., Cai K., Lin H., Liu Y., Meng H., Min Y., and Epstein A. J., “Fabricating of high-performance functional graphene fibers for micro-capacitive energy storage”. Scientific Reports, vol.6, 2016, pp. 1-8, doi: 10.1038/srep29534.
[11] Hallett C. and Johnston A., Fabric for Fashion: The Complete Guide:Natural and Man-made Fibers, China: Laurence King Publishing Ltd, 2014, pp. 185-187.
[12] Xu Z., Gao C., “Graphene chiral liquid crystals and macroscopic assembled fibres,” Nature Communications, December, 571 (2), 2011, pp. 1-9.
[13] Pei, S., Cheng, H., “The reduction of graphene oxide,” Carbon, vol.50, 2011, pp.3210-3228.
[14] Stankovich, S., Dikin, D.M., Piner, R.D., Kohlaas, K.A., Kleinhammes A., Jia, Y., Wu, Y., Nguyen, S.T., Ruoff, R.S., “Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide,” Carbon, vol.45, 2007, pp.1558-1565.
[15] Aboutalebi S.H., Jalili, R., Esrafilzadeh, D., Salari M., Gholamvand Z., Yamini S.A., Konstantinov, K., Shepherd, R.L., Chen, J., Moulton, S.E., Innis, P.C., Minett, A.I., Razal, J.M., Wallece, G.G., “High-performance multifunctional graphene yarns: toward wearable all-carbon energy storage textiles,” AcsNano, vol.8, 2014, No.3, pp. 2456-2466.
[16] Xiang, C., Young C., Wang X., “Large flake graphene oxide fibers with unconventional 100% knot efficiency and highly aligned small flake graphene oxide fibers,” Advanced Materials, September, vol.33 (25), 2013, pp. 4592-4597.
[17] Xu Z., Sun H., Zhao X., Gao C., “Graphene in macroscopic order: Liquid crystals and wet-spun fibers,” Advanced Materials, vol.25, 2013, pp.188-193.
[18] Xu Z., Liu Z., Sun H., “Highly electrically conductive ag-doped graphene fibers as stretchable conductors,” Advanced Materials, June, vol.23 (25), 2013, pp. 3249-3253.
[19] Zhao Y., Jiang C., Hu C., “Large-scale spinning assembly of neat, morphology-defined, graphene-based hollow fibers,” Acs Nano, February, vol.3 (7), 2013, pp. 2406-2412.
[20] Huang G., Hou C., Shao Y., Wang H., Zhang Q., Li Y. and Zhu M., “Highly strong and elastic graphene fibers prepared from universal graphene oxide precursors,” Scientific Reports, 4, 2014, 4248.
[21] Dong Z., Jiang C., Cheng H., Zhao Y., Shi G., Jiang L., Qu L., “Facile fabrication of light, flexible and multifunctional graphene fibers,” Advanced Materials, vol.24, 2012, pp. 1856-1861.
[22] Cheng H., Dong Z., Hu C., Zhao Y., Hu Y., Qu L., Chen N. and Dai L., “Textile electrodes woven by carbon nanotube–graphene hybrid fibers for flexible electrochemical capacitors,” Nanoscale, vol.5, 2013, 3428.
[23] Chen Q., Meng Y., Hu C., Zhao Y., Shao H. Chen N., Qu L., “MnO2-modified hierarchical graphene fiber electrochemical supercapacitor,” Journal of Power Sources, vol.247, 2014, pp.32-39.
[24] Liu Z., Xu Z., Hu X., and Gao C., “Lyotropic liquid crystal of polyacrylonitrile-grafted graphene oxide and its assembled continuous strong nacre-mimetic fibers,” Macromolecules, 46, 2013, 6931.
[25] Yang Z., Sun H., Chen T., Qiu L., Luo Y., Peng H., “Photovoltaic wire derived from a graphene composite fiber achieving an 8.45% energy conversion efficiency,” Angewandte Chemie, vol.125 (29), 2013, 7693.
[26] Ucar N, Gokceli G., Yuksek I. O, Onen A, Yavuz N. K., “Graphene oxide and graphene fiber produced by different nozzle size, feed rate and reduction time with Vitamin C,” accepted for publication in Journal of Industrial Textiles.