Effect of the Experimental Conditions on the Adsorption Capacities in the Removal of Pb2+ from Aqueous Solutions by the Hydroxyapatite Nanopowders
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Effect of the Experimental Conditions on the Adsorption Capacities in the Removal of Pb2+ from Aqueous Solutions by the Hydroxyapatite Nanopowders

Authors: Oral Lacin, Turan Calban, Fatih Sevim, Taner Celik

Abstract:

In this study, Pb2+ uptake by the hydroxyapatite nanopowders (n-Hap) from aqueous solutions was investigated by using batch adsorption techniques. The adsorption equilibrium studies were carried out as a function of contact time, adsorbent dosage, pH, temperature, and initial Pb2+ concentration. The results showed that the equilibrium time of adsorption was achieved within 60 min, and the effective pH was selected to be 5 (natural pH). The maximum adsorption capacity of Pb2+ on n-Hap was found as 565 mg.g-1. It is believed that the results obtained for adsorption may provide a background for the detailed mechanism investigations and the pilot and industrial scale applications.

Keywords: Nanopowders, hydroxyapatite, heavy metals, adsorption.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1125925

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References:


[1] Hao Guo, Yongzheng Ren, Xueliang Sun, Yadi Xu, Xuemei Li, Tiancheng Zhang, Jianxiong Kang and Dongqi Liu “Removal of Pb2+ from aqueous solutions by a high-efficiency resin”, Applied Surface Science, 283, 2013, pp.660–667.
[2] Jayakumar R, Menon D, Manzoor K, Nair SV and Tamura H, “Biomedical applications of chitin and chitosan based nanomaterials-A short review”, Carbohyd. Polym., 82(2), 2010, pp. 227–232.
[3] Pronczuk J, Bruné M-N and Gore F, “Children’s environmental health in developing countries”, Encyclopedia Environ. Health, 2011, pp. 601–610.
[4] Şahika Sena Bayazit , and İsmail İnci, “Adsorption of Pb(II) ions from aqueous solutions by carbon nanotubes oxidized different methods” Journal of Industrial and Engineering Chemistry, vol.19, 2013, pp. 2064–2071.
[5] A. Günay, E. Arslankaya, and I. Tosun, “Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics”, Journal of Hazardous Materials, vol.146, no.1-2, 2007, pp.362–371.
[6] S. E. Bailey, T. J. Olin, R. M. Bricka, and D. D. Adrian, “A review of potentially low-cost sorbents for heavy metals,” Water Research, vol.33, no.11, 1999, pp. 2469–2479.
[7] Q. Y. Ma, T. J. Logan, S. J. Traina, and J. A. Ryan, “Effects of NO3-, Cl-, F-, SO42-, and CO32- on Pb2+ immobilization by hydroxyapatite”, Environmental Science and Technology, vol.28, no.3, 1994, pp.408–418.
[8] D. E. Ellis, J. Terra, O. Warschkow et al., “A theoretical and experimental study of lead substitution in calcium hydroxyapatite”, Physical Chemistry Chemical Physics, vol.8, no.8, 2006, pp.967–976.
[9] Y. Xu and F. W. Schwartz, “Lead immobilization by hydroxyapatite in aqueous solutions”, Journal of Contaminant Hydrology, vol.15, no.3, 1994, pp.187–206.
[10] Q. Y. Ma, S. J. Traina, T. J. Logan, and J. A. Ryan, “In situ lead immobilization by apatite”, Environmental Science and Technology, vol.27, no.9, 1993, pp.1803–1810.
[11] C.K. Lee, H.S. Kim, J.H. Kwon, Environ. Eng. Res., vol.10, 2005, pp.205–212.
[12] J. Jeanjean, J.C. Rouchaud, L. Tran, M. Fedoroff, J. Radioanal. Nucl. Chem., vol.201, 1995, pp.529–539.
[13] Q.Y. Ma, S.J. Traina, T.J. Logan, J.A. Ryan, Environ. Sci. Technol., vol.27, 1993, pp.1803–1810.
[14] I. Smiciklas, A. Onjia, S. Raicevic, K. Janackovic, M. Mitric, J. Hazard. Mater., vol.152, 2008, pp.876–884.
[15] Feray Bakan, Oral Lacin and Hanifi Sarac, “A novel low temperature sol–gel synthesis process for thermally stable nano crystalline hydroxyapatite”, Powder Technology, vol.233, 2013, pp.295–302.
[16] A.A. Tahaa, Mohamed A. Shreadahb, A.M. Ahmeda and Hany Fathy Heiba, “Multi-component adsorption of Pb(II), Cd(II), and Ni(II) onto Egyptian Na-activated bentonite; equilibrium, kinetics, thermodynamics, and application for seawater desalination”, Journal of Environmental Chemical Engineering, 4, 2016, pp.1166–1180.
[17] M. Ghasemi, M. Naushad, N. Ghasemi and Y. Khosravi-fard, “Adsorption of Pb(II) from aqueous solution using new adsorbents prepared from agricultural waste: Adsorption isotherm and kinetic studies”, Journal of Industrial and Engineering Chemistry, vol.20, 2014, pp.2193–2199.
[18] Sayed A. Drweesha, Nady A. Fathy, Mohammed A. Wahba, Adli A. Hanna, Adel I.M. Akarish, Eman A.M. Elzahany, Iman Y. El-Sherif and Khaled S. Abou-El-Sherbini, “Equilibrium, kinetic and thermodynamic studies of Pb(II) adsorption from aqueous solutions on HCl-treated Egyptian kaolin”, Journal of Environmental Chemical Engineering, Vol.4, 2016, Pp.1674–1684.
[19] A.S. Mohamed, A.Z. Ghalia and A.K. Samia, “Simultaneous removal of copper(II), lead(II), zinc(II) and cadmium(II) from aqueous solutions by multi-walled carbon nanotubes.”, C. R. Chim., vol.15, 2012, pp.398–408.
[20] M. Imamoglu and O. Tekir, “Removal of copper(II) and lead(II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks.”, Desalination, vol.228, 2008, pp.108–113.