Influence of Iron Ore Mineralogy on Cluster Formation inside the Shaft Furnace
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32797
Influence of Iron Ore Mineralogy on Cluster Formation inside the Shaft Furnace

Authors: M. Bahgat, H. A. Hanafy, S. Lakdawala

Abstract:

Clustering phenomenon of pellets was observed frequently in shaft processes operating at higher temperatures. Clustering is a result of the growth of fibrous iron precipitates (iron whiskers) that become hooked to each other and finally become crystallized during the initial stages of metallization. If the pellet clustering is pronounced, sometimes leads to blocking inside the furnace and forced shutdown takes place. This work clarifies further the relation between metallic iron whisker growth and iron ore mineralogy. Various pellet sizes (6 – 12.0 & +12.0 mm) from three different ores (A, B & C) were (completely and partially) reduced at 985 oC with H2/CO gas mixture using thermos-gravimetric technique. It was found that reducibility increases by decreasing the iron ore pellet’s size. Ore (A) has the highest reducibility than ore (B) and ore (C). Increasing the iron ore pellet’s size leads to increase the probability of metallic iron whisker formation. Ore (A) has the highest tendency for metallic iron whisker formation than ore (B) and ore (C). The reduction reactions for all iron ores A, B and C are mainly controlled by diffusion reaction mechanism.

Keywords: Shaft furnace, cluster, metallic iron whisker, mineralogy, ferrous metallurgy.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1124393

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1960

References:


[1] H.R. John Kopfle, Direct reduction's role in the world steel industry, Ironmaking and Steelmaking 35 (2008) 254–259.
[2] Midrex technologies, Inc., 2010 world direct reduction statistics, http://www. Midrex.com, 2011.
[3] J. Fang, Theory of Non-Blast Furnace Ironmaking Process, Metallurgical Industry Press, Beijing, 2002.
[4] Ali Basdag, Ali Ihsan Arol, Coating of iron oxide pellets for direct reduction, Scandinavian Journal of Metallurgy 31 (2002) 229–233.
[5] P.L. Hooey, K. Zarins, A. Dahlstedt, H. Annersten, Behaviour of kaolinite coated olivine pellets in blast furnace, Ironmaking and Steelmaking 31 (2004) 333–341.
[6] K.S. Abdel-Halim, M.I. Nasr, A.A. El-Geassy, Developed model for reduction mechanismof iron ore pellets under load, Ironmaking and Steelmaking 38 (2011) 189–196.
[7] P.L.M. Wong, M.J. Kim, H.S. Kim, C.H. Choi, Sticking behaviour in direct reduction of iron ore, Ironmaking and Steelmaking 26 (1999) 53–57.
[8] Shoji Hayashi, Yoshiaki Iguchi, Factors affecting the sticking of fine iron ores during fluidized bed reduction, ISIJ International 32 (1992) 962–971.
[9] M.I.R.K.O. Komatina, Heinrich -W, The sticking problem during direct reduction, Metalurgija (2004) 309–328.
[10] J. Fang, Sticking problem in fluidized bed iron ore reduction, Iron and Steel 26 (1991) 11–15.
[11] Shoji Hayashi, Satoshi Sawai, Yoshiaki Iguchi, Influence of coating oxide and sulfur pressure on sticking during fluidized bed reduction of iron ores, ISIJ International 33 (1993) 1078–1087.
[12] W.L. Malte Bartels, John Nijenhuis, Freek Kapteijn, J. Ruud van Ommen, Agglomeration in fluidized beds at high temperatures: mechanisms, detection and prevention, Progress in Energy and Combustion Science 34 (2008) 633–666.
[13] D.R. Higgins, N.B. Gray, M.R. Davidson, Simulating particle agglomeration in the flash smelting reaction shaft, Minerals Engineering 22 (2009) 1251–1265.
[14] J.F. Gransden, J.S. Sheasby, The sticking of iron ore during reduction by hydrogen in a fluidized bed, Canadian Metallurgical Quarterly 13 (1974) 649–657.
[15] Shoji Hayashi, Sougo Sayama, Yoshiaki Iguchi, Relation between sulfur pressure and sticking of fine iron ores in fluidized bed reduction, ISIJ International 30 (1990) 722–730.
[16] Lingyun Yi, Zhucheng Huang, Tao Jiang, Powder Technology 235 (2013) 1001–1007
[17] Zhao, Z.-L., Tang, H.-Q., Guo, Z.-C., Journal of Iron and Steel Research 24 (11) (2012) , pp. 23-28
[18] T. Inami and K. Suzuki, Tetsu to Hagane, 80 (1994), 699-704.
[19] T. Inami and K. Suzuki, Tetsu to Hagane, 81 (1995), 1037-1042.
[20] D. H. St. John and P. C. Hayes, Met. Trans., 13B (1982), 117-124.
[21] D. H. St. John, S. P. Matthew and P. C. Hayes, Met. Trans., 15B (1984), 701-717.
[22] C. T. Rae and P. C. Hayes, Ind. Tech. Res. Inst., 1(2) (1986), 137-148.
[23] S. P. Matthew, T. R. Cho and P. C. Hayes, Met. Trans., 21B (1990), 733-741.
[24] R. Nicolle and A. Rist, Metallurgical Trensactions B, 10B (1979), 429.