Photocatalytic Cleaning Performance of Air Filters for a Binary Mixture
Commenced in January 2007
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Photocatalytic Cleaning Performance of Air Filters for a Binary Mixture

Authors: Lexuan Zhong, Chang-Seo Lee, Fariborz Haghighat, Stuart Batterman, John C. Little

Abstract:

Ultraviolet photocatalytic oxidation (UV-PCO) technology has been recommended as a green approach to health indoor environment when it is integrated into mechanical ventilation systems for inorganic and organic compounds removal as well as energy saving due to less outdoor air intakes. Although much research has been devoted to UV-PCO, limited information is available on the UV-PCO behavior tested by the mixtures in literature. This project investigated UV-PCO performance and by-product generation using a single and a mixture of acetone and MEK at 100 ppb each in a single-pass duct system in an effort to obtain knowledge associated with competitive photochemical reactions involved in. The experiments were performed at 20 % RH, 22 °C, and a gas flow rate of 128 m3/h (75 cfm). Results show that acetone and MEK mutually reduced each other’s PCO removal efficiency, particularly negative removal efficiency for acetone. These findings were different from previous observation of facilitatory effects on the adsorption of acetone and MEK on photocatalyst surfaces.

Keywords: By-products, inhibitory effect, mixture, photocatalytic oxidation.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1108945

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References:


[1] Mirzaei PA, Haghighat F. Approaches to study Urban Heat Island – Abilities and limitations. . Building and Environment. 2010;45:2192-201.
[2] ANSI/ASHRAE Standard 62.1-2013 - Ventilation for Acceptable Indoor Air Quality, American Society of Heating, Refrigerating, and Air-Conditioning Engineers, Inc., Atlanta.
[3] Jo WK, PARK KH. Heterogeneous photocatalysis of aromatic and chlorinated volatile organic compounds (VOCs) for non-occupational indoor air application. Chemosphere 2004: 57: 555-65.
[4] Jeong J, Sekiguchi K, Lee W, Sakamoto K. Photodegradation of gaseous volatile organic compounds (VOCs) using TiO2 photoirradiated by an ozone-producing UV lamp: decomposition characteristics, identification of by-products and water-soluble organic intermediates. J Photoch Photobio A. 2005;169:279-87.
[5] Sleiman M, Conchon P, Ferronato C, Chovelon JM. Photocatalytic oxidation of toluene at indoor air levels (ppbv): Towards a better assessment of conversion, reaction intermediates and mineralization. Appl Catal B-Environ. 2009;86:159-65.
[6] Zhong L, Haghighat F, Blondeau P, Kozinski J. Modeling and physical interpretation of photocatalytic oxidation efficiency in indoor air applications. Building and Environment. 2010;45:2689-97.
[7] Quici N, Vera ML, Choi H, Puma GL, Dionysiou DD, Litter MI, et al. Effect of key parameters on the photocatalytic oxidation of toluene at low concentrations in air under 254+185 nm UV irradiation. Appl Catal B-Environ. 2010;95:312-9.
[8] Zhong L, Haghighat F. Modeling and validation of a photocatalytic oxidation reactor for indoor environment applications. Chemical Engineering Science. 2011;66:5945-54.
[9] Destaillats H, Sleiman M, Sullivan DP, Jacquiod C, Sablayrolles J, Molins L. Key parameters influencing the performance of photocatalytic oxidation (PCO) air purification under realistic indoor conditions. Applied Catalysis B: Environmental. 2012;128:159-70.
[10] Geng, Q., Wang, Q., Zhang, B., 2012. Adsorption and photocatalytic oxidation of methanol-benzene binary mixture in an annular fluidized bed photocatalytic reactor. Industrial & Engineering Chemistry Research, 51, 15360-15373.
[11] Vildozo, D., Portela, R., Ferronato, C., Chovelon, J-M., 2011. Photocatalytic oxidation of 2-propanol/ toluene binary mixtures at indoor air concentration levels. Applied Catalysis B: Environmental, 107, 347-354.
[12] Twesme, T. M., Tompkins, D. T., Anderson, M. A., Root, T. W., 2006. Photocatalytic oxidation of low molecular weight alkanes: Observations with ZrO2-TiO2 supported thin films. Applied Catalysis B: Environmental, 64, 153-160.
[13] Lichtin, N. N., Avudaithai, M., Berman, E., Grayfer, A., 1996. TiO2-photocatalyzed oxidative degradation of binary mixtures of vaporized organic compounds. Solar Energy, 56 (5), 377-385.
[14] Zhang, M., An, T., Fu, J., Sheng, G., Wang, X., Hu, X., Ding, X., 2006. Photocatalytic degradation of mixed gaseous carbonyl compounds at low level on adsorptive TiO2/SiO2 photocatalyst using a fluidized bed reactor. Chemosphere, 64, 423-431.
[15] Zhong L, Haghighat F, Lee CS, Lakdawala N. Performance of ultraviolet photocatalytic oxidation for indoor air applications: systematic experimental evaluation. Journal of hazardous materials. 2013;261:130-8.
[16] Zhong L, Haghighat F, Lee C-S. Ultraviolet photocatalytic oxidation for indoor environment applications: Experimental validation of the model. Building and Environment. 2013;62:155-66.
[17] Lee, C-S., Zhong, L., Haghighat, F., Coulthrust, C. Evaluation of ozone removal performance of ultraviolet photocatalytic oxidation air cleaning systems, ASHRAE Annual Conference, Atlanta, USA, June 27-July 1, 2015.
[18] Zhong L, Lee CS, Haghighat F. Adsorption performance of titanium dioxide (TiO2) coated air filters for volatile organic compounds. Journal of hazardous materials. 2012;243:340-9.