Radio-Frequency Plasma Discharge Equipment for Conservation Treatments of Paper Supports
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32799
Radio-Frequency Plasma Discharge Equipment for Conservation Treatments of Paper Supports

Authors: Emil G. Ioanid, Viorica Frunză, Dorina Rusu, Ana Maria Vlad, Catalin Tanase, Simona Dunca

Abstract:

The application of cold Radio-Frequency (RF) plasma in the conservation of cultural heritage became important in the last decades due to the positive results obtained in decontamination treatments. This paper presents an equipment especially designed for cold RF plasma application on paper documents, developed within a research project. The equipment consists in two modules: the first one is designed for decontamination and cleaning treatments of any type of paper supports, while the second one can be used for coating friable papers with adequate polymers, for protection purposes. All these operations are carried out in cold radio-frequency plasma, working in gaseous nitrogen, at low pressure. In order to optimize the equipment parameters ancient paper samples infested with microorganisms have been treated in nitrogen plasma and the decontamination effects, as well as changes in surface properties (color, pH) were assessed. The microbiological analysis revealed complete decontamination at 6 minutes treatment duration; only minor modifications of the surface pH were found and the colorimetric analysis showed a slight yellowing of the support.

Keywords: Cultural heritage, nitrogen plasma, paper support.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1108833

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2552

References:


[1] E. Vassallo, L. Laguardia, D. Ricci, G. Bonizzoni “Innovative Plasma Processes for Consolidation of Biodeteriorated Ancient Papers”, Macromol. Symp., no. 238, pp. 46–51, 2006
[2] H. Szczepanowska, C. S. M. Lovett “A Study of the Removal and Prevention of Fungal Stains on Paper”. JAIC.,vol.31, no.2, pp. 147-160, 1992
[3] M. Totolin, D. Macocinschi, G. E. Ioanid, D. Filip, and A. Ioanid, Materials Supports for Cultural Heritage Objects Treated in Cold Plasma,” Optoelectron. Adv. Mater.-Rapid Commun., vol. 1, no. 12, pp. 309–314, 2007.
[4] L. Favre-Quattropani, P. Groening, D. Ramseyer, L. Schlapbach “The Protection of Metallic Archaeological Objects Using Plasma Polymer Coatings”, Surf Coat Technol. vol. 125, no. 1-3, pp. 377-382, 2000
[5] V. Veprek, C. Eckmann, J. Elmer, “Recent Progress in the Restoration of Archaeological Metallic Artefacts by Means of Low-Pressure Plasma Treatment”, Plasma Chem Plasma Process, vol. 8, no. 4, pp. 445–465. 1988
[6] J. Novakovic, O. Papadopoulou, P. Vassiliou, E. Filippaki, Y. Bassiakos “Plasma Reduction of Bronze Corrosion Developed under Long-Term Artificial Ageing” Anal Bioanal Chem., vol. 395 no. 7, pp. 2235–2244, 2009.
[7] E. G. Ioanid, A. Ioanid, D. E. Rusu, and F. Doroftei, “Surface Investigation of Some Medieval Silver Coins Cleaned in High Frequency Cold Plasma,” J. Cult. Heritage, vol. 12, no. 2, pp. 220 –226, 2011.
[8] M. I. Totolin, G. E. Ioanid, and I. Neamtu, “Plasma Chemistry and the Environment,” Environ. Eng. Manag. J., vol. 8, no. 6, pp. 1501–1507, 2009.
[9] M. Totolin, G. Cazacu, C. Vasile, “Cellulosic Materials Modification by Physical and Chemical Methods”, in Fine Structure of Papermaking Fibres, COST Action E54 Book, (eds. P. Ander, W. Bauer, S. Heinemann, P. Kallio, R. Passas and A. Treimanis), COST Office Brussels, pp. 27-38, 2011
[10] A. Comiotto, “Miniaturized Cold Atmospheric Plasma for the Conservation of Plastics in Modern and Contemporary Art,” CHIMIA Int. J. Chem., vol. 62, no. 11, pp. 877–881, 2008.
[11] U. Vohrer, I. Trick, J. Bernhard, C. Oehr, H. Brunner, “Plasma Treatment—An Increasing Technology for Paper Restoration?” Surf. Coat. Technol., vol. 142–144, pp. 1069–1073, Jul. 2001.
[12] E. G. Ioanid, A. Ioanid, D. E. Rusu, C. M. Popescu, I. Stoica, “Surface Changes upon high-frequency plasma treatment of Heritage Photographs,” J. Cult. Heritage, vol. 12, no. 4, pp. 399–407, 2011.
[13] E. G. Ioanid, S. Dunca, D. E. Rusu, C. Tanase, “Comparative Study on Decontamination Treatment of Paper-Based Materials in Corona Discharge and HF Cold Plasma,” Eur. Phys. J. Appl. Phys, vol. 58, no. 1, pp. 58, 2012.
[14] M. I. Totolin and I. Neamtu, “Positive Findings for Plasma Polymer (meth)Acrylate Thin Films in Heritage Protective Applications,” J. Cult. Heritage, vol. 12, no. 4, pp. 392–398, 2011.
[15] S. K. Rutledge, B. A. Banks, M. Forkapa, T. Stueber, E. Sechkar, K. Malinowski, “Atomic Oxygen Treatment as a Method of Recovering Smoke-Damaged Paintings,” J. Amer. Inst. Conservat., vol. 39, no. 1, pp. 65–74, 2000.
[16] E. G. Ioanid, D. E. Rusu, A. Ioanid, S. Dunca, and A. Muresan. (2009). Installation and Process for Preserving Objects (Online). Available: http://www.osim.ro/brevete/pbrev.html
[17] G. Beamson and D. Briggs, High Resolution XPS of Organic Polymers. New York, NY, USA: Wiley, 1992.
[18] E.G.Ioanid, D.Rusu, A.Ioanid, S.Dunca, A.Muresan, Patent Ro 122 396, 2009.
[19] Sarawut Rimdusit, Korapat Somsaeng, Prartana Kewsuwan, Chanchira Jubsilp, Sunan Tiptipakorn, “Comparison of Gamma Radiation Crosslinking and Chemical Crosslinking on Properties of Methylcellulose Hydrogel”, Engineering Journal, vol.16, no.4, pp. 15- 28, 2012.