@article{(Open Science Index):https://publications.waset.org/pdf/10002233,
	  title     = {Speciation of Iron (III) Oxide Nanoparticles and Other Paramagnetic Intermediates during High-Temperature Oxidative Pyrolysis of 1-Methylnaphthalene},
	  author    = {Michael P. Herring and  Lavrent Khachatryan and  Barry Dellinger},
	  country	= {},
	  institution	= {},
	  abstract     = {Low Temperature Matrix Isolation - Electron
Paramagnetic Resonance (LTMI-EPR) Spectroscopy was utilized to
identify the species of iron oxide nanoparticles generated during the
oxidative pyrolysis of 1-methylnaphthalene (1-MN). The otherwise
gas-phase reactions of 1--MN were impacted by a polypropylenimine
tetra-hexacontaamine dendrimer complexed with iron (III) nitrate
nonahydrate diluted in air under atmospheric conditions. The EPR
fine structure of Fe (III)2O3 nanoparticles clusters, characterized by gfactors
of 2.00, 2.28, 3.76 and 4.37 were detected on a cold finger
maintained at 77 K after accumulation over a multitude of
experiments. Additionally, a high valence Fe (IV) paramagnetic
intermediate and superoxide anion-radicals, O2•- adsorbed on
nanoparticle surfaces in the form of Fe (IV) --- O2•- were detected
from the quenching area of Zone 1 in the gas-phase.},
	    journal   = {International Journal of Chemical and Molecular Engineering},
	  volume    = {9},
	  number    = {7},
	  year      = {2015},
	  pages     = {870 - 878},
	  ee        = {https://publications.waset.org/pdf/10002233},
	  url   	= {https://publications.waset.org/vol/103},
	  bibsource = {https://publications.waset.org/},
	  issn  	= {eISSN: 1307-6892},
	  publisher = {World Academy of Science, Engineering and Technology},
	  index 	= {Open Science Index 103, 2015},
	}